Can all bulk-phase reactions be accelerated in microdroplets?

Literature Information

Publication Date 2017-03-14
DOI 10.1039/C6AN02225A
Impact Factor 4.616
Authors

Shibdas Banerjee, Elumalai Gnanamani, Xin Yan, Richard N. Zare


View Original

Abstract

Recent studies have shown that microdroplet reactions are markedly accelerated compared to the corresponding bulk-phase reactions. This raises the question whether all reactions can be sped up by this means. We present a counter example, and we show that the reaction mechanism in microdroplets can differ sharply from that in bulk, especially because of the distinct microdroplet surface environment. This analysis helps to guide us how to choose and control reactions in microdroplets and provides a possible perspective on utilizing microdroplet chemistry to scale up synthesis.

Related Literature

Spectral assignments and NMR parameter–structure relationships in borates using high-resolution 11B NMR and density functional theory

Oliver L. G. Alderman, Dinu Iuga, Andrew P. Howes, Diane Holland, Ray Dupree

2013-04-05 Paper

DOI: 10.1039/C3CP50772F

Self-discharge of electrochemical double layer capacitors

Andrzej Lewandowski, Pawel Jakobczyk, Maciej Galinski, Marcin Biegun

2013-03-22 Perspective

DOI: 10.1039/C3CP44612C

Lone-pair distribution and plumbite network formation in high lead silicate glass, 80PbO·20SiO2

Oliver L. G. Alderman, Alex C. Hannon, Diane Holland, Steve Feller, Gloria Lehr, Adam J. Vitale, Uwe Hoppe, Martin v. Zimmerman, Anke Watenphul

2013-04-29 Paper

DOI: 10.1039/C3CP51348C

Raman spectral characteristics of 4-aminobenzenethiol adsorbed on ZnO nanorod arrays

Kwan Kim, Kyung Lock Kim, Kuan Soo Shin

2013-05-09 Paper

DOI: 10.1039/C3CP51204E

Compositional-asymmetry influenced non-linear optical processes of plasmonic nanoparticle dimers

Anke Horneber, Anne-Laure Baudrion, Pierre-Michel Adam, Alfred J. Meixner, Dai Zhang

2013-03-07 Communication

DOI: 10.1039/C3CP43349H

Physical and chemical transformations of highly compressed carbon dioxide at bond energies

Choong-Shik Yoo

2013-03-21 Perspective

DOI: 10.1039/C3CP50761K

Chronoamperometric study of membrane electrode assembly operation in continuous flow photoelectrochemical water splitting

Jan Rongé, Dorien Nijs, Stef Kerkhofs, Kasper Masschaele, Johan A. Martens

2013-04-11 Paper

DOI: 10.1039/C3CP50890K

Sieving di-branched from mono-branched and linear alkanes using ZIF-8: experimental proof and theoretical explanation

Marjo C. Mittelmeijer-Hazeleger, Miguel Angelo Granato, Vanessa F. Duarte Martins, Alírio E. Rodrigues, Gadi Rothenberg

2013-05-02 Paper

DOI: 10.1039/C3CP44381G

Tip enhanced Raman spectroscopy (TERS) as a probe for the buckling distortion in silicene

Deepthi Jose, A. Nijamudheen

2013-04-18 Communication

DOI: 10.1039/C3CP51028J

You might also like

Compound Q&A

What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?

N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...

52818-63-0N-(4-Methoxybenzyl)-...
Compound Q&A

What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?

When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...

1050507-06-6Ethyl 4-(2-chlorophe...
Compound Q&A

What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?

Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...

628-39-7Diethyldiselane
Compound Q&A

What is the market or research trend for oxocopper (CAS: 12053-18-8)?

The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...

12053-18-8oxocopper; oxo-(oxoc...
Compound Q&A

What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?

The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...

1268519-54-55-{[(2-Methyl-2-prop...
Compound Q&A

What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?

2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...

35981-63-62-(1-Pyrrolidinyl)-4...
Compound Q&A

What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?

2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...

91556-75-12-(3-Pyridinyl)-1-az...
Compound Q&A

How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?

(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...

129704-91-2(S)-Alpha-allyl-prol...
Compound Q&A

What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?

3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...

4857-42-53-Methyl-1,2-oxazole...
Compound Q&A

How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?

Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...

1281816-04-3Lys-SMCC-DM1

Source Journal

Analyst

Analyst
CiteScore: 7.8
Self-citation Rate: 5.6%
Articles per Year: 653

Analyst publishes analytical and bioanalytical research that reports premier fundamental discoveries and inventions, and the applications of those discoveries, unconfined by traditional discipline barriers.

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.