Incorporation of benzothiadiazole into the backbone of 1,2,5,6-naphthalenediimide based copolymers, enabling much improved film crystallinity and charge carrier mobility
Literature Information
Zheng Zhao, Zhongli Wang, Congwu Ge, Xu Zhang, Xiaodi Yang, Xike Gao
By incorporating benzothiadiazole units into the main chain of 1,2,5,6-naphthalenediimide (iso-NDI) and thiophene based copolymers, we report herein a new high performance donor–acceptor (D–A) polymer, P(iso-NDI-TBT), with much improved film crystallinity and charge carrier mobility. The optical, electrochemical, and charge transport properties as well as the photovoltaic performance were investigated. Bottom-gate bottom-contact organic field-effect transistors (OFETs) based on the thin films of P(iso-NDI-TBT) show a high hole mobility of up to 0.82 cm2 V−1 s−1, which is a record value for the 1,2,5,6-NDI based polymers. In addition, the photovoltaic performance of P(iso-NDI-TBT) was also studied, affording a power conversion efficiency (PCE) of 1.5% with a high open-circuit voltage (Voc) of 0.9 V. Our work provides important clues for designing high performance D–A polymeric semiconductors and also demonstrates that 1,2,5,6-NDIs are promising building blocks for constructing new polymer semiconductors.
Related Literature
The co-curing process of a benzoxazine-cyanate system and the thermal properties of the copolymers
Xiaodan Li, Yi Gu
DOI: 10.1039/C1PY00379H
Polyelectrolyte uptake by PEMs: Impact of salt concentration
Xingjie Zan, Bo Peng, David A. Hoagland, Zhaohui Su
DOI: 10.1039/C1PY00280E
Synthesis of monodisperse SiO2/P(DVB-SO3H)/SiO2/P(DVB-SO3H) tetra-layer polyelectrolyte microspheres and the corresponding hollow P(DVB-SO3H)polyelectrolyte microspheres with a shell-in-shell structure
Min Ji, Hongli Liu, Xinlin Yang
DOI: 10.1039/C0PY00228C
Metalloenzymatic radical polymerization using alkyl halides as initiators
Yeap-Hung Ng, Fabio di Lena, Christina L. L. Chai
DOI: 10.1039/C0PY00139B
Synthesis, characterization and cellular internalization of poly(2-hydroxyethyl methacrylate) bearing α-d-mannopyranose
Makoto Obata, Mayumi Shimizu, Tomoko Ohta, Aya Matsushige, Kaoru Iwai, Shiho Hirohara, Masao Tanihara
DOI: 10.1039/C0PY00326C
RAFT polymerization and thermal behavior of trimethylphosphonium polystyrenes for anion exchange membranes
Kristoffer K. Stokes, Joshua A. Orlicki, Frederick L. Beyer
DOI: 10.1039/C0PY00293C
Sequential self-repetitive reaction toward wholly aromatic polyimides with highly stable optical nonlinearity
Hsun-Lien Lin, Tzong-Yuan Juang, Li-Hsin Chan, Rong-Ho Lee, Shenghong A. Dai, Ying-Ling Liu, Wen-Chiung Su, Ru-Jong Jeng
DOI: 10.1039/C0PY00157K
Formation of nanoporous materials via mild retro-Diels–Alder chemistry
Mathias Glassner, James P. Blinco, Christopher Barner-Kowollik
DOI: 10.1039/C0PY00267D
Thiol–isocyanate “click” reactions: rapid development of functional polymeric surfaces
Ryan M. Hensarling, Santosh B. Rahane, Arthur P. LeBlanc, Bradley J. Sparks, Evan M. White, Jason Locklin, Derek L. Patton
DOI: 10.1039/C0PY00292E
Design and examination of an antioxidant-containing polyphosphazene scaffold for tissue engineering
Nicole L. Morozowich, Jessica L. Nichol, Ryan J. Mondschein, Harry R. Allcock
DOI: 10.1039/C2PY00570K
You might also like
What is 3-Fluoro-2-methylbenzylamine (CAS: 771573-36-5)?
3-Fluoro-2-methylbenzylamine is an organic compound with the CAS number 771573-3...
Is Tert-butyl 2-(oxetan-3-ylidene)acetate (CAS: 1207175-03-8) safe?
Tert-butyl 2-(oxetan-3-ylidene)acetate is considered safe for its intended uses ...
What precautions should be taken when handling 4-Acetyl-2-fluorobenzonitrile (CAS: 214760-18-6)?
Proper personal protective equipment (PPE) such as gloves, goggles, and a lab co...
How is 2-Ethyl-4-methyl-1,3-thiazole (CAS: 15679-12-6) typically synthesized?
2-Ethyl-4-methyl-1,3-thiazole is commonly synthesized via the reaction of thiour...
How should 5',5''-([2,2'-Bithiophene]-5,5'-diyl)bis(([1,1':3',1''-terphenyl]-4,4''-dicarboxylic acid)) (CAS: 1227780-71-3) be stored?
This compound should be stored in a cool, dry place away from direct sunlight an...
What regulatory guidelines apply to L-Lysine Acetate Salt (CAS: 52315-92-1)?
L-Lysine Acetate Salt (CAS: 52315-92-1) is subject to various regulatory guideli...
Is 6-Fluoro-3-hydroxy-2-pyrazinecarboxamide (CAS: 259793-96-9) safe?
6-Fluoro-3-hydroxy-2-pyrazinecarboxamide (CAS: 259793-96-9) is generally conside...
What are the physical and chemical properties of 1,1'-Sulfonylbis(1H-imidazole) (CAS: 7189-69-7)?
1,1'-Sulfonylbis(1H-imidazole) is a crystalline solid with a molecular weight of...
What industries use 4-methyl-7-nitro-1H-indole-3-carbonitrile (CAS: 289483-82-5)?
4-Methyl-7-nitro-1H-indole-3-carbonitrile (CAS: 289483-82-5) is primarily used i...
How should waste containing 5-Bromo-3-indolyl-beta-galactoside (CAS: 97753-82-7) be handled?
Waste containing 5-Bromo-3-indolyl-beta-galactoside (CAS: 97753-82-7) should be ...
Source Journal
Polymer Chemistry

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.












![Benzyl spiro[indole-3,4'-piperidine]-1(2H)-carboxylate hydrochloride (1:1) structure Benzyl spiro[indole-3,4'-piperidine]-1(2H)-carboxylate hydrochloride (1:1) structure](https://static.chemtradehub.com/structs/159/159635-46-8-8de0.webp)

