Formation of nanoporous materials via mild retro-Diels–Alder chemistry

Literature Information

Publication Date 2010-10-04
DOI 10.1039/C0PY00267D
Impact Factor 5.582
Authors

Mathias Glassner, James P. Blinco, Christopher Barner-Kowollik


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Abstract

Poly(styrene)-block-poly(ethylene oxide) copolymers synthesized via the combination of reversible addition fragmentation chain transfer (RAFT) polymerization and hetero Diels–Alder (HDA) cycloaddition can be cleaved in the solid state by a retro-HDA reaction occurring at 90 °C. Nanoporous films can be prepared from these polymers using a simple heating and washing procedure.

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