Inverse internal conversion in C4− below the electron detachment threshold

Literature Information

Publication Date 2015-07-07
DOI 10.1039/C5CP02549D
Impact Factor 3.676
Authors

Naoko Kono, Takeshi Furukawa, Hajime Tanuma, Jun Matsumoto, Haruo Shiromaru, Toshiyuki Azuma, Kaveh Najafian, Maria Susanne Pettersson, Bertil Dynefors, Klavs Hansen


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Abstract

Inverse internal conversion followed by recurrent fluorescence was observed as a fast decay (10 μs range) in the time profile of neutral yields from photo-excited C4− molecular ions. We also elucidated the contribution of such electronic radiative cooling to the C4− ions with internal energy far below the detachment threshold by an alternative novel approach, observing the laser wavelength and storage time dependence (ms range) of the total yield of the photo-induced neutrals.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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