Enhanced saturation magnetization in buckypaper-films of thin walled carbon nanostructures filled with Fe3C, FeCo, FeNi, CoNi, Co and Ni crystals: the key role of Cl

Literature Information

Publication Date 2015-06-08
DOI 10.1039/C5CP02425K
Impact Factor 3.676
Authors

Jian Guo, Mu Lan, Shanling Wang, Yi He, Sijie Zhang, Gang Xiang, Filippo S. Boi


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Abstract

We report an advanced chemical vapour deposition approach which allows the direct in situ synthesis of cm-length ultrathin buckypapers comprising carbon nanostructures filled with Fe3C, FeCo, FeNi, CoNi, Co and Ni by sublimation and pyrolysis of single or combined metallocenes with very low quantities of dichlorobenzene. As a result, extremely high saturation magnetizations of 117 emu g−1, 90 emu g−1 and 80 emu g−1 are obtained for the specific cases of Fe3C, FeCo and FeNi, respectively, while variable saturation magnetizations of 70 emu g−1, 58 emu g−1 and 6.7 emu g−1 are obtained for Co, CoNi and Ni respectively.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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