X-ray spectroscopy characterization of azobenzene-functionalized triazatriangulenium adlayers on Au(111) surfaces
Literature Information
Sandra Ulrich, Ulrich Jung, Thomas Strunskus, Christian Schütt, Andreas Bloedorn, Sonja Lemke, Eric Ludwig, Lutz Kipp, Franz Faupel, Olaf Magnussen, Rainer Herges
Triazatriangulenium (TATA) platform molecules allow the preparation of functionalized surfaces with well-defined lateral spacings of freestanding functional groups. Using scanning tunneling microscopy, synchrotron-based X-ray photoelectron spectroscopy, near edge X-ray absorption fine structure spectroscopy and complementary density functional theory calculations the chemical composition and orientational order of adlayers of functionalized azobenzene containing TATA platform molecules were characterized. According to these studies the molecules are chemically intact on the surface after self-assembly from solution and exhibit a well-defined adsorption geometry where the azobenzene units are oriented almost perpendicular to the surface.
Related Literature
Thiolactone chemistry, a versatile platform for macromolecular engineering
Nicolas Illy, Emma Mongkhoun
DOI: 10.1039/D2PY00731B
Protected amine-functional initiators for the synthesis of α-amine homo- and heterotelechelic poly(2-ethyl-2-oxazoline)s
Zihnil A. I. Mazrad, May Lai, Thomas P. Davis, Joseph A. Nicolazzo, Meike N. Leiske
DOI: 10.1039/D2PY00649A
A dual initiator approach for oxygen tolerant RAFT polymerization
Nicholas G. Taylor, Marcus H. Reis, Travis P. Varner, Johann L. Rapp, Alexis Sarabia, Frank A. Leibfarth
DOI: 10.1039/D2PY00603K
Functional pH-responsive polymers containing dynamic enaminone linkages for the release of active organic amines
Spyridon Efstathiou, Congkai Ma, Despina Coursari, Georgios Patias, Lucas Al-Shok, David M. Haddleton
DOI: 10.1039/D2PY00167E
Mechanistic insights into the pressure-induced polymerization of aryl/perfluoroaryl co-crystals
Margaret C. Gerthoffer, Bohan Xu, Sikai Wu, Jordan Cox, Steven Huss, Shalisa M. Oburn, Steven A. Lopez, Elizabeth Elacqua
DOI: 10.1039/D1PY01387D
Effect of radical copolymerization of the (oxa)norbornene end-group of RAFT-prepared macromonomers on bottlebrush copolymer synthesis via ROMP
Daniel J. Keddie
DOI: 10.1039/D1PY01599K
Synthesis of a triptycene-containing dioxazine benzoxazine monomer and a main-chain triptycene-polydimethysiloxane-benzoxazine copolymer with excellent comprehensive properties
Rui Yang, Lin Xie, Nan Li, Pablo Froimowicz, Kan Zhang
DOI: 10.1039/D2PY00244B
Optically reconfigurable shape memory metallo-polymer mediated by a carbolong complex and radically exchangeable covalent bond
Liulin Yang, Haibo Zhao, Yulin Xie, Pufan Ouyang, Yonghong Ruan, Jiangxi Chen, Wengui Weng, Xumin He, Haiping Xia
DOI: 10.1039/D2PY00192F
Design of selective divalent chain transfer agents for coordinative chain transfer polymerization of ethylene and its copolymerization with butadiene
Julien Thuilliez
DOI: 10.1039/D2PY00155A
You might also like
What are the main uses of 1-(3-Aminophenyl)-3-[(3R)-1-(3,3-dimethyl-2-oxobutyl)-2-oxo-5-(2-pyridinyl)-2,3-dihydro-1H-1,4-benzodiazepin-3-yl]urea (CAS: 155412-88-7)?
This compound is mainly used as an intermediate in the synthesis of antipsychoti...
How should waste containing 1-(D-Ribofuranosyl)-1,4-dihydro-3-pyridinecarboxamide (CAS: 19132-12-8) be handled?
Waste containing 1-(D-Ribofuranosyl)-1,4-dihydro-3-pyridinecarboxamide (CAS: 191...
What regulatory guidelines apply to 2-Methyl-2-propanyl 3-bromo-3-(hydroxymethyl)-1-azetidinecarboxylate (CAS: 2007919-81-3)?
2-Methyl-2-propanyl 3-bromo-3-(hydroxymethyl)-1-azetidinecarboxylate (CAS: 20079...
What is N-(4-Chloro-2-pyridinyl)acetamide (CAS: 245056-66-0)?
N-(4-Chloro-2-pyridinyl)acetamide (CAS: 245056-66-0) is a chemical compound with...
What is 5-Chloro-2-hydroxybenzoic acid (CAS: 321-14-2)?
5-Chloro-2-hydroxybenzoic acid, also known as 5-chlorosalicylic acid, is an arom...
What precautions should be taken when handling 1,1-Dichloro-1-fluoroethane (CAS: 1717-00-6)?
When handling 1,1-Dichloro-1-fluoroethane (CAS: 1717-00-6), it is important to u...
What are the physical and chemical properties of Fmoc-(2S,3R)-3-phenylpyrrolidine-2-carboxylic acid (CAS: 281655-32-1)?
Fmoc-(2S,3R)-3-phenylpyrrolidine-2-carboxylic acid is a white crystalline solid ...
What are the main uses of 4-Amino-5-bromo-2-pyridinecarboxylic acid (CAS: 1363381-01-4)?
4-Amino-5-bromo-2-pyridinecarboxylic acid is primarily used as a precursor in th...
What precautions should be taken when handling (S)-tert-butyl 2-((2-(4-bromophenyl)-2-oxoethyl)carbamoyl)pyrrolidine-1-carboxylate (CAS: 1007881-98-2)?
Handling this compound should be done with personal protective equipment (PPE) i...
What precautions should be taken when handling 8-bromo-2,2-dimethyl-3,4-dihydro-2H-1,4-benzoxazin-3-one (CAS: 688363-73-7)?
When handling 8-bromo-2,2-dimethyl-3,4-dihydro-2H-1,4-benzoxazin-3-one, use prop...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![Methyl 4-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)bicyclo[2.2.2]octane-1-carboxylate structure Methyl 4-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)bicyclo[2.2.2]octane-1-carboxylate structure](https://static.chemtradehub.com/structs/943/943845-74-7-b7e5.webp)


![tert-Butyl N-[(2-chloropyridin-4-yl)methyl]carbamate structure tert-Butyl N-[(2-chloropyridin-4-yl)methyl]carbamate structure](https://static.chemtradehub.com/structs/916/916210-27-0-9f95.webp)