Thiolactone chemistry, a versatile platform for macromolecular engineering
Literature Information
Publication Date
2022-07-25
DOI
10.1039/D2PY00731B
Impact Factor
5.582
Authors
Nicolas Illy, Emma Mongkhoun
View Original
Abstract
Thiolactones are often described as latent thiols. They can be ring-opened by hydroxy or amine groups releasing thiols, which can further react with a large variety of functional groups. Based on this one-pot cascade reaction, versatile and powerful tools have been developed for macromolecular engineering. This review covers the different uses of γ-thiobutyrolactones in polymer chemistry either as thiolation agents, as linkers, as ring-opening polymerization monomers, as reactant in stepwise polymerization, as components of initiating systems, or as functional handles for double post-modification reactions.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![6-Benzyl-4,5,6,7-tetrahydro-1H-pyrazolo[3,4-c]pyridin-3(2H)-one structure](https://static.chemtradehub.com/structs/909/909187-64-0-f54f.webp "6-Benzyl-4,5,6,7-tetrahydro-1H-pyrazolo[3,4-c]pyridin-3(2H)-one structure")
6-Benzyl-4,5,6,7-tetrahydro-1H-pyrazolo[3,4-c]pyridin-3(2H)-one
CAS Number:
909187-64-0
Molecular Formula:
C13H15N3O
3-Chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-pyridinamine
CAS Number:
1032758-99-8
Molecular Formula:
C11H16BClN2O2
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