Platinum–hydrogen vibrations and low energy electronic excitations of 13-atom Pt nanoclusters
Literature Information
Melanie Keppeler
Two Pt−H vibrational bands at 1679 cm−1 and 1392 cm−1 observed with 13-atom Pt clusters supported in LTL zeolite by Fourier Transform Infrared (FTIR) spectroscopy confirms that H atoms bridge two Pt atoms across the edges of the metal cluster. An additional broad absorption band centred near 2200 cm−1 which exhibits some substructure is assigned to low energy electronic excitations across the HOMO–LUMO gap of the developing band structure of the nanocluster.
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