Achiral benzophenoneligand–rhodium complex with chiral diamine activator for high enantiocontrol in asymmetric transfer hydrogenation

Literature Information

Publication Date 2006-05-03
DOI 10.1039/B517585B
Impact Factor 6.222
Authors

Koichi Mikami, Kazuki Wakabayashi, Yukinori Yusa, Kohsuke Aikawa


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Abstract

The chirality of an achiral benzophenone-based rhodium complex can be controlled by chiral diamines to afford significantly high enantioselectivity in the catalytic asymmetric transfer hydrogenation of ketones (up to 99% ee, 99% yield).

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