Achiral benzophenoneligand–rhodium complex with chiral diamine activator for high enantiocontrol in asymmetric transfer hydrogenation
Literature Information
Koichi Mikami, Kazuki Wakabayashi, Yukinori Yusa, Kohsuke Aikawa
The chirality of an achiral benzophenone-based rhodium complex can be controlled by chiral diamines to afford significantly high enantioselectivity in the catalytic asymmetric transfer hydrogenation of ketones (up to 99% ee, 99% yield).
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