Simple transformation of crystalline chiral natural anions to liquid medium and their use to induce chirality
Literature Information
Publication Date
2006-05-10
DOI
10.1039/B600816J
Impact Factor
6.222
Authors
Luís C. Branco, Pedro M. P. Gois, Nuno M. T. Lourenço, Vanya B. Kurteva, Carlos A. M. Afonso
View Original
Abstract
New chiral ionic liquids can be prepared simply by combining the tetra-n-hexyl-dimethylguanidinium cation with readily available chiral anions and used as an asymmetric inducing agent as demonstrated for catalytic Rh(II) carbenoid C–H insertion and Sharpless dihydroxylation.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
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