Simple transformation of crystalline chiral natural anions to liquid medium and their use to induce chirality
Literature Information
Publication Date
2006-05-10
DOI
10.1039/B600816J
Impact Factor
6.222
Authors
Luís C. Branco, Pedro M. P. Gois, Nuno M. T. Lourenço, Vanya B. Kurteva, Carlos A. M. Afonso
View Original
Abstract
New chiral ionic liquids can be prepared simply by combining the tetra-n-hexyl-dimethylguanidinium cation with readily available chiral anions and used as an asymmetric inducing agent as demonstrated for catalytic Rh(II) carbenoid C–H insertion and Sharpless dihydroxylation.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
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Sodium (2Z)-7-{[(2R)-2-amino-2-carboxyethyl]sulfanyl}-2-({[(1S)-2,2-dimethylcyclopropyl]carbonyl}amino)-2-heptenoate
CAS Number:
81129-83-1
Molecular Formula:
C16H25N2NaO5S
Trichloro(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane
CAS Number:
78560-45-9
Molecular Formula:
C8H4Cl3F13Si
![Sodium 3-[(E)-(4-anilinophenyl)diazenyl]benzenesulfonate structure](https://static.chemtradehub.com/structs/587/587-98-4-035f.webp "Sodium 3-[(E)-(4-anilinophenyl)diazenyl]benzenesulfonate structure")
Sodium 3-[(E)-(4-anilinophenyl)diazenyl]benzenesulfonate
CAS Number:
587-98-4
Molecular Formula:
C18H14N3NaO3S
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