Cyclopolymerization of dimethyl dipropargylmalonate in supercritical carbon dioxide to give a highly regular polyene containing predominantly five-membered rings
Literature Information
Ji Won Pack, Young-Jae Hur, Hwayong Kim, Youn-Woo Lee
Poly(dimethyl dipropargylmalonate) synthesized in scCO2 contained more than 95% five-membered rings, i.e., highly regular polyene was produced, which shows carbon dioxide as a reaction medium plays a significant role in determining a highly selective polymer structure.
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