Cyclopolymerization of dimethyl dipropargylmalonate in supercritical carbon dioxide to give a highly regular polyene containing predominantly five-membered rings

Literature Information

Publication Date 2005-09-21
DOI 10.1039/B510046A
Impact Factor 6.222
Authors

Ji Won Pack, Young-Jae Hur, Hwayong Kim, Youn-Woo Lee


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Abstract

Poly(dimethyl dipropargylmalonate) synthesized in scCO2 contained more than 95% five-membered rings, i.e., highly regular polyene was produced, which shows carbon dioxide as a reaction medium plays a significant role in determining a highly selective polymer structure.

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DOI: 10.1039/C9AY90157D

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