Well-controlled reversible addition–fragmentation chain transfer radical polymerisation under ultraviolet radiation at ambient temperature
Literature Information
Lican Lu, Nianfa Yang, Yuanli Cai
Controlled reversible addition–fragmentation chain transfer radical polymerisation of methyl acrylate was carried out under long-wave (λ ≥ 365 nm) ultraviolet radiation using an acylphosphine oxide as a photoinitiator at ambient temperature; the polymerisation shows a “living” character at high conversions of polymerisation and leads to well-defined polymers with narrow polydispersities (Mw/Mn < 1.1).
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