Well-controlled reversible addition–fragmentation chain transfer radical polymerisation under ultraviolet radiation at ambient temperature

Literature Information

Publication Date 2005-10-10
DOI 10.1039/B512057H
Impact Factor 6.222
Authors

Lican Lu, Nianfa Yang, Yuanli Cai


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Abstract

Controlled reversible addition–fragmentation chain transfer radical polymerisation of methyl acrylate was carried out under long-wave (λ ≥ 365 nm) ultraviolet radiation using an acylphosphine oxide as a photoinitiator at ambient temperature; the polymerisation shows a “living” character at high conversions of polymerisation and leads to well-defined polymers with narrow polydispersities (Mw/Mn < 1.1).

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