Isolation of stable non cyclic 1,2-disulfoxides. Revisiting the thermolysis of S-aryl sulfinimines‡

Literature Information

Publication Date 2014-09-01
DOI 10.1039/C4CC05751A
Impact Factor 6.222
Authors

Willian Lewis, Robert A. Stockman


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Abstract

The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via initial Cope elimination, dimerisation of the produced sulfenic acid to a thiosulfinate, and subsequent disproportionation of the thiosulfinate.

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