Evidence of orbital mixing for KrXe and ArXe excited states in the vacuum ultraviolet
Literature Information
D. M. Mao, X. K. Hu, Y. J. Shi, R. H. Lipson
The dissociation limits for two KrXe Rydberg states near 80000 cm−1 have been reassigned using single-photon vacuum ultraviolet (VUV) laser resonance enhanced multiphoton ionization (REMPI)/time-of-flight (TOF) mass spectrometry. These new assignments follow from spectral intensity changes that occur when the excited states are populated by single-photon excitation instead of a two-photon transition. The observations can be rationalized on the basis of strong 6p–5d orbital mixing on the Xe center induced by ground state Kr in the excited state of the dimer. ArXe transitions in this region have also been found by (1 + 1′) REMPI. There is also strong intensity evidence here for strong p–d mixing. Isotopic transition wavenumbers for the newly observed ArXe bands are provided, but molecular constants have not been derived due to severe interstate perturbations. Where possible the relationship between these results and our current understanding of the rare gas kinetics leading to gain in the infrared Xe laser is discussed.
Related Literature
2D silver nanocrystal ordering modulated by various substrates and revealed using oxygen plasma treatment
Emilie Klecha, Imad Arfaoui, Johannes Richardi, Dorothée Ingert, Marie-Paule Pileni
DOI: 10.1039/C0CP01237H
Molecular organization of hydrophobic molecules and co-adsorbed water in SBA-15 ordered mesoporous silica material
Randy Mellaerts, Maarten B. J. Roeffaers, Kristof Houthoofd, Michiel Van Speybroeck, Gert De Cremer, Jasper A. G. Jammaer, Guy Van den Mooter, Patrick Augustijns, Johan Hofkens, Johan A. Martens
DOI: 10.1039/C0CP01640C
One-pot generation of mesoporous carbon supported nanocrystalline calcium oxides capable of efficient CO2 capture over a wide range of temperatures
Na Hao, Gongkui Xiao, Liying Liu, Paul Webley
DOI: 10.1039/C0CP01807D
Charging of ionic liquid surfaces under X-ray irradiation: the measurement of absolute binding energies by XPS
Ignacio J. Villar-Garcia, Emily F. Smith, Alasdair W. Taylor, Fulian Qiu, Kevin R. J. Lovelock, Robert G. Jones, Peter Licence
DOI: 10.1039/C0CP01587C
Electrochemical activation of molecular nitrogen at the Ir/YSZ interface
Ilia Valov, Bjoern Luerssen, Eva Mutoro, Luca Gregoratti, Roger A. De Souza, Thomas Bredow, Sebastian Günther, Alexei Barinov, Pavel Dudin, Manfred Martin, Jürgen Janek
DOI: 10.1039/C0CP01024C
Size and morphology of assemblies formed by DNA and lysozyme in dilute aqueous mixtures
Anna M. Carnerup, John Janiak, Karin Schillén, Maria da Graça Miguel
DOI: 10.1039/C0CP01220C
Ultra-slow water diffusion in aqueous sucrose glasses
Vacharaporn Soonsin, Bei P. Luo, Ulrich K. Krieger, Claudia Marcolli, Thomas Peter, Thomas Koop
DOI: 10.1039/C0CP01273D
Long distance energy transfer in a polymer matrix doped with a perylenedye
Franziska Fennel, Stefan Lochbrunner
DOI: 10.1039/C0CP01211D
Direct electrochemisty and electrocatalysis of anthraquinone-monosulfonate/polyaniline hybrid film synthesized by a novel electrochemical doping-dedoping-redoping method on pre-activated spectroscopically pure graphite surface
Guoquan Zhang, Fenglin Yang
DOI: 10.1039/C0CP00608D
You might also like
What are the main uses of 1H-Indazole-6-carbonitrile (CAS: 141290-59-7)?
1H-Indazole-6-carbonitrile finds applications in pharmaceuticals, where it serve...
How should waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) be handled?
Waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) should be collecte...
What industries use Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide (CAS: 68291-98-5)?
Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide is primarily used in pharmac...
Are there alternatives to Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxylate (CAS: 741709-66-0) in synthesis?
Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxyla...
How should waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) be handled?
Waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) should be manage...
What is 6-Formyl-2-pyridinecarboxylic acid (CAS: 499214-11-8)?
6-Formyl-2-pyridinecarboxylic acid is an organic compound with the molecular for...
What is the market or research trend for 3-(3,4-dimethoxyphenyl)-2,5-dimethyl-N-(2-morpholin-4-ylethyl)pyrazolo[1,5-a]pyrimidin-7-amine (CAS: 900874-91-1)?
Research trends for this compound indicate a focus on its potential applications...
How is 9H-Tribenzo[b,d,f]azepine (CAS: 29875-73-8) typically synthesized?
9H-Tribenzo[b,d,f]azepine is typically synthesized via a multi-step process invo...
How is 1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxylic acid (CAS: 1797982-51-4) typically synthesized?
1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxyli...
How should waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: 671820-52-3) be handled?
Waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: ...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![Sodium 3-[(E)-(4-anilinophenyl)diazenyl]benzenesulfonate structure Sodium 3-[(E)-(4-anilinophenyl)diazenyl]benzenesulfonate structure](https://static.chemtradehub.com/structs/587/587-98-4-035f.webp)
![(1S)-1,5-Anhydro-1-[3-(1-benzothiophen-2-ylmethyl)-4-fluorophenyl]-D-glucitol structure (1S)-1,5-Anhydro-1-[3-(1-benzothiophen-2-ylmethyl)-4-fluorophenyl]-D-glucitol structure](https://static.chemtradehub.com/structs/761/761423-87-4-dbeb.webp)

