4-Cyclohexene-1,2-dicarboxylic acid, 1,2-dimethyl ester, (1R,2R)-rel-
CAS Number:
17673-68-6
Molecular Formula:
C10H14O4
Photo-cross-linkable star-shaped polymers with poly(ethylene glycol) and renewable cardanol side groups: synthesis, characterization, and application to antifouling coatings for filtration membranes
Literature Information
Publication Date
2013-07-11
DOI
10.1039/C3PY00756A
Impact Factor
5.582
Authors
Dong-Gyun Kim, Hyo Kang, Yong-Seok Choi, Sungsoo Han, Jong-Chan Lee
View Original
Abstract
Star-shaped polymers (SPCs) containing poly(ethylene glycol) (PEG) and renewable cardanol side groups were synthesized by atom transfer radical polymerization (ATRP). Water-soluble SPCs were turned into water-insoluble materials by self-cross-linking reaction of the unsaturated hydrocarbon chains of cardanol moieties upon UV irradiation. The SPC-coated membranes with UV curing exhibited noticeably higher bio- and oil-fouling resistance than the bare polysulfone (PSf) membrane during filtration experiments, whereas the SPC-coated membranes without UV curing showed a large flux-decline caused by fouling compared to that of the bare membrane, because SPCs were washed out during filtration. The enhanced antifouling properties of the SPC-coated membranes with UV curing were ascribed to a large quantity of PEG moieties on the surfaces stabilized by the cross-linked polymeric structure, leading to decreased interactions with proteins and oils.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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CAS Number:
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Molecular Formula:
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