Probing RbBr solvation in freestanding sub-2 nm water clusters

Literature Information

Publication Date 2017-09-04
DOI 10.1039/C7CP04398H
Impact Factor 3.676
Authors

Lauri Hautala, Kari Jänkälä, Mikko-Heikki Mikkelä, Paavo Turunen, Nønne L. Prisle, Minna Patanen, Maxim Tchaplyguine, Marko Huttula


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Abstract

Concentration dependent solvation of RbBr in freestanding sub-2 nm water clusters was studied using core level photoelectron spectroscopy with synchrotron radiation. Spectral features recorded from dilute to saturated clusters indicate that either solvent shared or contact ion pairs are present in increasing amount when the concentration exceeds 2 mol kg−1. For comparison, spectra from anhydrous RbBr clusters are also presented.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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