The importance of ligand reactions in Cu(0)-mediated living radical polymerisation of acrylates
Literature Information
Publication Date
2013-03-04
DOI
10.1039/C3PY00270E
Impact Factor
5.582
Authors
Athina Anastasaki, Christopher Waldron, Paul Wilson, Ronan McHale, David M. Haddleton
View Original
Abstract
Ligand mediated termination events occur during the homo-polymerisation of methyl (MA) and butyl (BA) acrylate under SET-LRP (Cu(0) mediated) conditions. Careful optimization of [initiator]/[ligand] (Me6Tren) ratios is required to reduce termination in order to achieve optimum polymerisation.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
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