![1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane structure](https://static.chemtradehub.com/structs/97-/97-77-8-f3e4.webp "1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane structure")
1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane
CAS Number:
97-77-8
Molecular Formula:
C10H20N2S4
Using reversibility of the dynamic covalent bond to create porosity in highly ordered polymer thin films under mild conditions and nano-pore functionalization in the gas phase
Literature Information
Publication Date
2013-03-22
DOI
10.1039/C3PY00200D
Impact Factor
5.582
Authors
Jingyi Rao, Anzar Khan
View Original
Abstract
Phase-separating polystyrene (PS) and polyethylene glycol (PEG) polymers are connected through a hydrazone-based reversible covalent bond to afford a PS–CHN–PEG diblock copolymer. This novel dynamic covalent copolymer assembles into a nano-structured cylindrical morphology in thin films. Reversal of the hydrazone linkage and removal of PEG–hydrazide under mild conditions afford a nano-porous membrane featuring a chemically reactive functionality in the nano-pores. Availability of these reactive groups for further thin film functionalization is demonstrated by re-establishing the imine bond with a small molecule amine. This modification strategy does not require any coupling reagent, solvent, or high temperature. Therefore, a gas-phase technique is sufficient for film functionalization purposes.
Related Literature
The isomerisation of (Z)-3-[2H1]-phenylprop-2-enone as a measure of the rate of hydroperoxide addition in Weitz–Scheffer and Juliá–Colonna epoxidations
David R. Kelly, Eva Caroff, Robert W. Flood, William Heal, Stanley M. Roberts
2004-08-25
Communication
DOI: 10.1039/B404389H
Estimates of internal energies of vaporisation of some room temperature ionic liquids
Konrad Swiderski, Andrew McLean, Charles M. Gordon, D. Huw Vaughan
2004-09-07
Communication
DOI: 10.1039/B408334B
Electrodeposition of monodispersed Fe nanocrystals from an ionic liquid
C. L. Aravinda, W. Freyland
2004-10-19
Communication
DOI: 10.1039/B409861G
Electrophilicity parameters for σ-complexation by uncharged electron-deficient aromatic and heteroaromatic structures
François Terrier, Régis Goumont, Taoufik Boubaker, Erwin Buncel
2004-09-30
Communication
DOI: 10.1039/B410356D
Reversible folding/unfolding of linear molecular strands into helical channel-like complexes upon proton-modulated binding and release of metal ions
Adrian-Mihail Stadler, Nathalie Kyritsakas, Jean-Marie Lehn
2004-08-11
Communication
DOI: 10.1039/B407168A
Unsaturated 1,2-amino alcohols and ethers from aziridines and organolithiums
David M. Hodgson, Bogdan Štefane, Timothy J. Miles, Jason Witherington
2004-08-24
Communication
DOI: 10.1039/B409486G
New reactions in water: metal-free conversion of alcohols and ketones into α-iodoketones
José Barluenga, María Marco-Arias, Francisco González-Bobes, Alfredo Ballesteros, José M. González
2004-10-04
Communication
DOI: 10.1039/B411227J
The mechanism of the oxidative addition of aryl halides to Pd-catalysts: a DFT investigation
Lukas J. Gooßen, Debasis Koley, Holger Hermann, Walter Thiel
2004-08-20
Communication
DOI: 10.1039/B409144B
Bundles of identical double-walled carbon nanotubes
J.-F. Colomer, L. Henrard, P. Launois, G. Van Tendeloo, A. A. Lucas, Ph. Lambin
2004-09-30
Communication
DOI: 10.1039/B410930A
A thermally stable nanoporous nickel 5-sulfoisophthalate; crystal structure and adsorption properties
Dae Sung Kim, Paul M. Forster, Ronan Le Toquin, Anthony K. Cheetham
2004-08-17
Communication
DOI: 10.1039/B408535C
You might also like
Compound Q&A
What is 1-(2,4,6-Trifluorophenyl)ethanol (CAS: 1250113-83-7)?
1-(2,4,6-Trifluorophenyl)ethanol is an organic compound with the CAS number 1250...
1250113-83-71-(2,4,6-Trifluoroph...
Compound Q&A
Is 1-(2,4-Dimethoxybenzyl)-4-(hydroxymethyl)-2-pyrrolidinone (CAS: 919111-34-5) safe?
1-(2,4-Dimethoxybenzyl)-4-(hydroxymethyl)-2-pyrrolidinone (CAS: 919111-34-5) is ...
919111-34-51-(2,4-Dimethoxybenz...
Compound Q&A
What are the physical and chemical properties of (7S,15R)-6β,15-Diacetoxy-7α,20-epoxy-7-hydroxykaura-2,16-dien-1-one (CAS: 51419-51-3)?
(7S,15R)-6β,15-Diacetoxy-7α,20-epoxy-7-hydroxykaura-2,16-dien-1-one is a crystal...
51419-51-3(7S,15R)-6β,15-Diace...
Compound Q&A
What regulatory guidelines apply to rac-ethyl (1r,4r)-4-hydroxycyclohexane-1-carboxylate, trans (CAS: 3618-04-0)?
The compound rac-ethyl (1r,4r)-4-hydroxycyclohexane-1-carboxylate, trans (CAS: 3...
3618-04-0rac-ethyl (1r,4r)-4-...
Compound Q&A
What is the market or research trend for 2-(2,4-Difluorophenoxy)-3-nitropyridine (CAS: 175135-62-3)?
The market for 2-(2,4-Difluorophenoxy)-3-nitropyridine (CAS: 175135-62-3) is cur...
175135-62-32-(2,4-Difluoropheno...
Compound Q&A
What are the main uses of 6-Diazo-5-oxo-L-norleucine (CAS: 157-03-9)?
The main uses of 6-Diazo-5-oxo-L-norleucine (CAS: 157-03-9) include research in ...
157-03-96-Diazo-5-oxo-L-norl...
Compound Q&A
What precautions should be taken when handling 2-Aminoethyl-mono-amide-DOTA-tris(tBu ester) (CAS: 173308-19-5)?
When handling 2-Aminoethyl-mono-amide-DOTA-tris(tBu ester) (CAS: 173308-19-5), i...
173308-19-52-Aminoethyl-mono-am...
Compound Q&A
How is 5-Methylimidazo[1,2-a]pyridine-3-carbaldehyde (CAS: 178488-37-4) typically synthesized?
5-Methylimidazo[1,2-a]pyridine-3-carbaldehyde (CAS: 178488-37-4) can be synthesi...
178488-37-45-Methylimidazo[1,2-...
Compound Q&A
Are there alternatives to 2,4,6-Trihydroxyisophthalaldehyde (CAS: 4396-13-8) in synthesis?
There are alternative reagents that can be used in the synthesis of 2,4,6-Trihyd...
4396-13-82,4,6-Trihydroxyisop...
Compound Q&A
What is (2Z)-3-(5-Fluoro-1H-indol-3-yl)-2-sulfanylacrylic acid (CAS: 179461-52-0)?
(2Z)-3-(5-Fluoro-1H-indol-3-yl)-2-sulfanylacrylic acid is a chemical compound wi...
179461-52-0(2Z)-3-(5-Fluoro-1H-...
Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
6-amino-1,3-dimethyl-1,2,3,4-tetrahydropyrimidine-2,4-dione
CAS Number:
6642-31-5
Molecular Formula:
C6H9N3O2
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.