Adsorption and diffusion in thin films of nanoporous metal–organic frameworks: ferrocene in SURMOF Cu2(ndc)2(dabco)

Literature Information

Publication Date 2013-04-12
DOI 10.1039/C3CP50578B
Impact Factor 3.676
Authors


View Original

Abstract

The adsorption and diffusion of ferrocene (FC) in thin MOF films of type Cu2(ndc)2(dabco) were studied by X-ray diffraction and using a quartz-crystal microbalance (QCM) at different temperatures. A quantitative analysis of the uptake curves in the QCM during loading with FC from the gas phase yields 0.19 FC compounds per pore at a temperature of 305 K and of 0.06 at 335 K, respectively. From an analysis of this temperature dependence we obtain an adsorption enthalpy of −30 kJ mol−1. A quantitative analysis of the time dependence of the QCM uptake curves yields very small diffusivities on the order of 10−19 to 10−17 m2 s−1, while the activation energy for diffusion amounts to +90 kJ mol−1. These results show that using a quartz crystal microbalance for uptake studies in SURMOFs is a valuable tool for investigating very slowly diffusing compounds in nanoporous materials.

Related Literature

Ratiometric fluorescent probes based on through-bond energy transfer of cyanine donors to near-infrared hemicyanine acceptors for mitochondrial pH detection and monitoring of mitophagy

Shuai Xia, Yibin Zhang, Nick Whisman, Jianheng Bi, Tessa E. Steenwinkel, Shulin Wan, Jerry Medford, Momoko Tajiri, Rudy L. Luck, Thomas Werner, Haiying Liu

2019-12-11 Paper

DOI: 10.1039/C9TB02302J

High resolution magic angle spinning NMR as a tool for unveiling the molecular enantiorecognition of omeprazole by amylose-based chiral phase

Juliana Cristina Barreiro, Tiago de Campos Lourenço, Lorena Mara A. Silva, Tiago Venâncio, Quezia Bezerra Cass

2013-12-17 Paper

DOI: 10.1039/C3AN02029K

Simple enrichment and analysis of plasma lysophosphatidic acids

Jialu Wang, Martha Sibrian-Vazquez, Jorge O. Escobedo, Mark Lowry, Lei Wang, Yu-Hsuan Chu, Richard G. Moore, Robert M. Strongin

2013-09-26 Paper

DOI: 10.1039/C3AN01168B

Inside front cover

Cover

DOI: 10.1039/C9AN90013F

A rapid and highly sensitive paper-based colorimetric device for the on-site screening of ammonia gas

Kawin Khachornsakkul, Kuen-Hau Hung, Jung-Jung Chang, Wijitar Dungchai, Chih-Hsin Chen

2021-03-02 Paper

DOI: 10.1039/D1AN00032B

A reusable, reagent-less free chlorine sensor using gold thin film electrode

Arif Ul Alam, Dennis Clyne

2021-03-03 Paper

DOI: 10.1039/D1AN00038A

Development and comparison of various rod-shaped mini-reference electrode compositions based on Ag/AgCl for potentiometric applications

Mustafa Nigde, Ismail Agir, Rıdvan Yıldırım, Ibrahim Isildak

2021-12-17 Paper

DOI: 10.1039/D1AN01754C

Laminin-511 and recombinant vitronectin supplementation enables human pluripotent stem cell culture and differentiation on conventional tissue culture polystyrene surfaces in xeno-free conditions

Ya-Chu Liu, Lee-Kiat Ban, Hsin-Ting Lee, Yu-Tang Chang, Yun-Ting Lin, Her-Young Su, Shih-Tien Hsu

2021-09-24 Paper

DOI: 10.1039/D1TB01878G

You might also like

Compound Q&A

What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?

N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...

52818-63-0N-(4-Methoxybenzyl)-...
Compound Q&A

What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?

When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...

1050507-06-6Ethyl 4-(2-chlorophe...
Compound Q&A

What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?

Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...

628-39-7Diethyldiselane
Compound Q&A

What is the market or research trend for oxocopper (CAS: 12053-18-8)?

The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...

12053-18-8oxocopper; oxo-(oxoc...
Compound Q&A

What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?

The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...

1268519-54-55-{[(2-Methyl-2-prop...
Compound Q&A

What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?

2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...

35981-63-62-(1-Pyrrolidinyl)-4...
Compound Q&A

What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?

2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...

91556-75-12-(3-Pyridinyl)-1-az...
Compound Q&A

How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?

(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...

129704-91-2(S)-Alpha-allyl-prol...
Compound Q&A

What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?

3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...

4857-42-53-Methyl-1,2-oxazole...
Compound Q&A

How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?

Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...

1281816-04-3Lys-SMCC-DM1

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.