Role of the organic linker in the early stages of the templated synthesis of PMOs

Literature Information

Publication Date 2013-03-06
DOI 10.1039/C3CP50193K
Impact Factor 3.676
Authors

Ryusuke Futamura, Miguel Jorge, José R. B. Gomes


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Abstract

Classical MD simulations for surfactant–bromide–water solutions containing several organosilicate precursors show that the presence or absence of molecular-scale periodicity in the pore walls of PMOs is dictated by the strength of the surfactant micelle–organosilica interaction and by the relative flexibility and orientation of the organic linker.

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