Giant reduction of the phase transition temperature for beryllium doped VO2

Literature Information

Publication Date 2013-02-01
DOI 10.1039/C3CP44476G
Impact Factor 3.676
Authors

Jiajia Zhang, Haiyan He, Yi Xie


View Original

Abstract

We propose a route to largely decrease the transition temperature for the insulator–metal transition of VO2 by doping with beryllium atoms. Our first-principles calculations show that the doped beryllium atoms can unprecedentedly decrease the phase transition temperature by 58 K per at% Be, which exceeds any doping attempts reported for VO2. Furthermore, it is found that the transition temperature of the Be-doped VO2 can be further lowered by applying external uniaxial pressure. A combination of Be-doping and external pressure realizes the occurrence of the phase transition at the desired room temperature. The nature of these findings is revealed to be essentially relevant to the strain-induced dimerization of V–V chains in the R-phased VO2.

Related Literature

A handheld device for potential point-of-care screening of cancer‡

Cheng-Chung Chang, Ta-Chau Chang, Li-Jen Liao, Pei-Jen Lou, Wenjun Xie, Edward S. Yeung

2007-06-08 Paper

DOI: 10.1039/B617733F

Quantitative assessment of human whole blood RNA as a potential biomarker for infectious disease

Paul Dickinson, Thorsten Forster, Mizanur Khondoker, Marie Craigon, Alan Ross, Petter Storm, Stewart Burgess, Paul Lacaze, Benjamin J. Stenson, Peter Ghazal

2007-10-31 Paper

DOI: 10.1039/B707122C

Modified secured principal component regression for detection of unexpected chromatographic features in herbal fingerprints

Yun Hu, Yi-Zeng Liang, Pei-Shan Xie, Yukihiro Ozaki

2006-01-23 Paper

DOI: 10.1039/B513365C

Progress in developing polymerized crystalline colloidal array sensors for point-of-care detection of myocardial ischemia

Justin T. Baca, David N. Finegold, Sanford A. Asher

2008-01-18 Paper

DOI: 10.1039/B712482A

Direct acoustic profiling of DNA hybridisation using HSV type 1 viral sequences

Yıldız Uludağ, Xin Li, Heather Coleman, Stacey Efstathiou, Matthew A. Cooper

2007-09-21 Paper

DOI: 10.1039/B711850C

Distinction of malignant melanoma and epidermis using IR micro-spectroscopy and statistical methods

Z. Hammody, S. Argov, R. K. Sahu, E. Cagnano, R. Moreh, S. Mordechai

2008-01-16 Paper

DOI: 10.1039/B712040K

A ‘turn-on’ FRET peptide sensor based on the mercury bindingprotein MerP

Brianna R. White, Howard M. Liljestrand, James A. Holcombe

2007-11-12 Paper

DOI: 10.1039/B711777A

SERS detection of environmental pollutants in humic acid–gold nanoparticle composite materials

Ramon A. Alvarez-Puebla, David S. dos Santos, Jr., Ricardo F. Aroca

2007-09-24 Paper

DOI: 10.1039/B711361G

Evaluation of partial least-squares with second-order advantage for the multi-way spectroscopic analysis of complex biological samples in the presence of analyte–background interactions

María J. Culzoni, Héctor C. Goicoechea, Ariana P. Pagani, Miguel A. Cabezón, Alejandro C. Olivieri

2006-04-11 Paper

DOI: 10.1039/B603383K

Stable isotope labelling and FPLC–ICP-SFMS for the accurate determination of clinical iron status parameters in human serum

M. Estela del Castillo Busto, Maria Montes-Bayón, Jörg Bettmer, Alfredo Sanz-Medel

2008-01-17 Paper

DOI: 10.1039/B715311B

You might also like

Compound Q&A

How should waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane be handled?

Waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane (...

100751-65-3[(6-Bromo-2-naphthyl...
Compound Q&A

How is 7-Fluoro-4-isoquinolinecarboxylic acid (CAS: 1841081-40-0) typically synthesized?

7-Fluoro-4-isoquinolinecarboxylic acid can be synthesized via a multi-step proce...

1841081-40-07-Fluoro-4-isoquinol...
Compound Q&A

What are the physical and chemical properties of 2,3,5,6-Tetrabromothieno[3,2-b]thiophene (CAS: 124638-53-5)?

2,3,5,6-Tetrabromothieno[3,2-b]thiophene is a crystalline compound with a high m...

124638-53-52,3,5,6-Tetrabromoth...
Compound Q&A

Is 1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indole-4-carboxamide (CAS: 1542705-92-9) safe?

1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indol...

1542705-92-91-[4-(Benzylamino)-7...
Compound Q&A

What is the market or research trend for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3-methyl-4-oxo- (CAS: 113942-30-6)?

The market for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3...

113942-30-6Imidazo[5,1-d]-1,2,3...
Compound Q&A

What is 3-(Triisopropylsilyl)propiolaldehyde (CAS: 163271-80-5)?

3-(Triisopropylsilyl)propiolaldehyde is a synthetic organic compound with the CA...

163271-80-53-(Triisopropylsilyl...
Compound Q&A

What regulatory guidelines apply to 6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1)?

6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1) is subject to various regu...

81721-87-16-Nitro-2H-1,4-benzo...
Compound Q&A

How should waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piperazinyl)acetic acid (CAS: 885272-91-3) be handled?

Waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piper...

885272-91-3(3-Fluorophenyl)(4-{...
Compound Q&A

What are the physical and chemical properties of N,N'-4,4'-Biphenyldiyldiisonicotinamide (CAS: 55119-40-9)?

N,N'-4,4'-Biphenyldiyldiisonicotinamide is a white crystalline solid with a mole...

55119-40-9N,N'-4,4'-Biphenyldi...
Compound Q&A

What industries use 6-Bromo-8-fluoro-2-quinazolinol (CAS: 1036756-15-6)?

6-Bromo-8-fluoro-2-quinazolinol is primarily used in the pharmaceutical industry...

1036756-15-66-Bromo-8-fluoro-2-q...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.