Strong-pump strong-probe spectroscopy: effects of higher excited electronic states

Literature Information

Publication Date 2013-03-22
DOI 10.1039/C3CP44454F
Impact Factor 3.676
Authors

Maxim F. Gelin, Dassia Egorova, Wolfgang Domcke


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Abstract

The present paper is devoted to the simulation of (integral and dispersed) pump–probe signals in the nonperturbative regime for a series of material systems with multiple electronic states and excited-state absorption. We show that strong-pump strong-probe spectroscopy permits the probing of vibrational wavepackets in high-lying and/or short-lived excited electronic states with a time resolution which is not limited by the pulse durations. The field strength can be regarded as an additional experimentally controllable parameter, which can be tuned to maximize the spectroscopic information for a given material system.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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