Tunable band gap and hydrogen adsorption property of a two-dimensional porous polymer by nitrogen substitution
Literature Information
Ruifeng Lu, Zhaoshun Meng, Erjun Kan, Feng Li, Dewei Rao, Zelin Lu, Jinchao Qian, Haiping Wu
After substitution of carbon by nitrogen, the electronic structures of the porous graphene have been studied by the density functional theory calculations. The N substitutional site without hydrogen passivation leads to a tunable energy gap of the two-dimensional porous polymer, depending on the number of N atoms in a unit cell. Moreover, the increasing number of N in an aromatic ring enhances the binding energies between hydrogen molecules and pre-adsorbed Li atoms from 1H2 to 3H2. Thus, porous polymer materials through controllable synthesis techniques will improve their potential applications in photosplitting of water as well as hydrogen storage.
Related Literature
Polymerization of methyl methacrylate by latent pre-catalysts based on CO2-protected N-heterocyclic carbenes
Stefan Naumann, Friedrich Georg Schmidt, Roman Schowner, Wolfgang Frey
DOI: 10.1039/C3PY00073G
Organocatalyzed controlled ROP of β-lactones towards poly(hydroxyalkanoate)s: from β-butyrolactone to benzyl β-malolactone polymers
Cédric G. Jaffredo, Jean-François Carpentier, Sophie M. Guillaume
DOI: 10.1039/C3PY00401E
High Tg thermosetting resins from resveratrol
Jessica J. Cash, Matthew C. Davis, Michael D. Ford, Thomas J. Groshens, Andrew J. Guenthner, Benjamin G. Harvey, Kevin R. Lamison, Joseph M. Mabry, Heather A. Meylemans, Josiah T. Reams, Christopher M. Sahagun
DOI: 10.1039/C3PY00438D
Faster cyclopolymerisation of 4,4-disubstituted 1,7-octadiynes through an enhanced Thorpe–Ingold effect
Hyeon Park, Ho-Keun Lee, Tae-Lim Choi
DOI: 10.1039/C3PY00556A
Post-polymerization modification of reactive polymers derived from vinylcyclopropane: 1. synthesis and thermo-responsive behaviour
Denis H. Seuyep N., Gerrit A. Luinstra, Patrick Theato
DOI: 10.1039/C3PY00109A
A nondestructive, statistical method for determination of initiation efficiency: dipentaerythritol-aided synthesis of ternary ABC3 miktoarm stars using a combined “arm-first” and “core-first” approach
Alexander A. Steinschulte, Bjoern Schulte, Natascha Drude, Michael Erberich, Christian Herbert, Jun Okuda, Martin Möller, Felix A. Plamper
DOI: 10.1039/C3PY00444A
RAFT polymerization of dimethyl(methacryloyloxy)methyl phosphonate and its phosphonic acid derivative: a new opportunity for phosphorus-based materials
Benjamin Canniccioni, Sophie Monge, Ghislain David, Jean-Jacques Robin
DOI: 10.1039/C3PY00426K
Hybrid organic–inorganic nanomaterial sensors for selective detection of Au3+ using rhodamine-based modified polyacrylic acid (PAA)-coated FeNPs
Noi Niamsa, Chatthai Kaewtong, Weerapol Srinonmuang, Banchob Wanno, Buncha Pulpoka, Thawatchai Tuntulani
DOI: 10.1039/C3PY00229B
Conjugated polymers with 2,7-linked 3,6-difluorocarbazole as donor unit for high efficiency polymer solar cells
Chun Du, Weiwei Li, Yan Duan, Cuihong Li, Huanli Dong, Jia Zhu, Wenping Hu, Zhishan Bo
DOI: 10.1039/C3PY00177F
You might also like
Is 6-(3-Fluorophenyl)picolinic acid (CAS: 887982-40-3) safe?
6-(3-Fluorophenyl)picolinic acid is generally considered safe for laboratory use...
What industries use (3R)-3-Pyrrolidinol (CAS: 2799-21-5)?
(3R)-3-Pyrrolidinol is used in the pharmaceutical industry as a precursor for dr...
What precautions should be taken when handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-8)?
When handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-...
How is 1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone (CAS: 90734-71-7) typically synthesized?
1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone is often synthesized via a mult...
What is the market or research trend for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1)?
The market for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1) remains steady,...
What is Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate (CAS: 1019008-21-9)?
Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate is a chemical compound wit...
What regulatory guidelines apply to 1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1)?
1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1) falls under the classi...
Is 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07-4) safe?
The safety of 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07...
Is Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate (CAS: 22785-43-9) safe?
Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate is generally safe when handled wi...
How should 1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine (CAS: 928657-21-0) be stored?
1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine s...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













![Benzyl spiro[indole-3,4'-piperidine]-1(2H)-carboxylate hydrochloride (1:1) structure Benzyl spiro[indole-3,4'-piperidine]-1(2H)-carboxylate hydrochloride (1:1) structure](https://static.chemtradehub.com/structs/159/159635-46-8-8de0.webp)
