Electro-catalytic oxidative cleavage of lignin in a protic ionic liquid

Literature Information

Publication Date 2012-02-07
DOI 10.1039/C2CP23596J
Impact Factor 3.676
Authors

Elena Reichert, Reiner Wintringer, Dietrich A. Volmer, Rolf Hempelmann


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Abstract

Lignin is a component of lignocellulosic biomass and a promising matrix for recovering important renewable aromatic compounds. We present a new approach of electro-oxidative cleavage of lignin, dissolved in a special protic ionic liquid, using an anode with particular electro-catalytic activity. As appropriate ionic liquid triethylammonium methanesulfonate was identified, synthesised, explored for dissolution of alkali-lignin and used for electrolysis of 5 wt.% lignin solutions. As appropriate anode material, oxidation-stable ruthenium–vanadium–titanium mixed oxide electrodes were prepared and explored for their electro-catalytic activity. The electrolysis was performed at several potentials in the range from 1.0 V to 1.5 V (vs. an Ag pseudo reference electrode). A wide range of aromatic fragments was identified as cleavage products by means of GC-MS and HPLC measurements.

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Physical Chemistry Chemical Physics
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