The synthesis of isostructural Mo2+porphyrin and N-confused porphyrin complexes
Literature Information
John D. Harvey, Janet L. Shaw, Richard S. Herrick, Christopher J. Ziegler
We have synthesized the first early transition metal N-confused porphyrin complex Mo(NCTPP)(pip)2; this species is isostructural to its normal porphyrin analog Mo(TPP)(pip)2 but exhibits significant electronic differences arising from the inversion of a single pyrrolic group.
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