syn-Selective asymmetric cross-aldol reactions between aldehydes and glyoxylic acid derivatives catalyzed by an axially chiral amino sulfonamide‡
Literature Information
Publication Date
2011-09-05
DOI
10.1039/C1CC14347F
Impact Factor
6.222
Authors
Taichi Kano, Akira Noishiki, Ryu Sakamoto, Keiji Maruoka
View Original
Abstract
syn-Selective asymmetric cross-aldol reactions of aldehydes with tert-butyl glyoxylate and glyoxamide were realized by the use of an axially chiral amino sulfonamide (S)-1. The cross-aldol products obtained are densely functionalized and readily converted to synthetically useful and important chiral building blocks such as γ-lactone and γ-lactam.
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Chemical Communications
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