From atactic to isotactic CO/p-methylstyrenecopolymer by proper modification of Pd(ii) catalysts bearing achiral α-diimines
Literature Information
Barbara Binotti, Carla Carfagna, Cristiano Zuccaccia, Alceo Macchioni
Cationic Pd(II) complexes modified with achiral C2v-symmetric α-diimine ligands allow preparation of atactic or isotactic stereoblock CO/p-methylstyrene copolymers; both catalyst activity and polyketone microstructure depend on the choice of α-diimine substituents and counterion.
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