Synthesis and structure of [{Sn(μ–PCy)}3(Na·PMDETA)2], containing an electron-deficient [{Sn(μ–PCy)}3]2− dianion

Literature Information

Publication Date 2003-05-06
DOI 10.1039/B300522D
Impact Factor 6.222
Authors

Paula Alvarez-Bercedo, Andrew D. Bond, Robert Haigh, Alexander D. Hopkins, Gavin T. Lawson, Mary McPartlin, David Moncrieff, Marta E. Gonzalez Mosquera, Jeremy M. Rawson, Anthony D. Woods, Dominic S. Wright


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Abstract

The reaction of CyPHNa with Sn(NMe2)2 in the presence of PMDETA (= {Me2NCH2CH2}2NMe) gives the title compound [{Sn(μ–PCy)}3(Na·PMDETA)2] (1), containing an electron-deficient [(Sn(μ–PCy)}]32− dianion with a novel two-electron, three centre (2e–3c) bonding arrangement.

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