Synthesis and structure of [{Sn(μ–PCy)}3(Na·PMDETA)2], containing an electron-deficient [{Sn(μ–PCy)}3]2− dianion
Literature Information
Paula Alvarez-Bercedo, Andrew D. Bond, Robert Haigh, Alexander D. Hopkins, Gavin T. Lawson, Mary McPartlin, David Moncrieff, Marta E. Gonzalez Mosquera, Jeremy M. Rawson, Anthony D. Woods, Dominic S. Wright
The reaction of CyPHNa with Sn(NMe2)2 in the presence of PMDETA (= {Me2NCH2CH2}2NMe) gives the title compound [{Sn(μ–PCy)}3(Na·PMDETA)2] (1), containing an electron-deficient [(Sn(μ–PCy)}]32− dianion with a novel two-electron, three centre (2e–3c) bonding arrangement.
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