Recent advances in entropy-driven ring-opening polymerizations
Literature Information
Publication Date
2010-12-01
DOI
10.1039/C0PY00328J
Impact Factor
5.582
Authors
Satu Strandman, Julien E. Gautrot, X. X. Zhu
View Original
Abstract
Entropy-driven ring-opening polymerization (ED-ROP) of unstrained macrocyclic monomers and/or oligomers employs the ring-chain equilibria between macrocycles and their corresponding polymers and the associated increase of conformational freedom to achieve high molecular weight materials. The principles of building macrocyclic compounds, their use in ED-ROP, and the practical considerations of polymerizations are described, and recent progress in this area is discussed through selected examples. The various polymerization techniques used for ED-ROP are discussed, including anionic, radical, coordination/insertion, ring-opening metathesis, and enzymatic polymerization methods. Emphasis is placed on the potential of ED-ROP in the synthesis of biomaterials and the development of enzyme-catalyzed green systems.
Related Literature
Experimental and theoretical investigation of long-wavelength fluorescence emission in push–pull benzazoles: intramolecular proton transfer or charge transfer in the excited state?
Guilherme Wiethaus, Josene Maria Toldo, Fabiano da Silveira Santos, Rodrigo da Costa Duarte, Paulo Fernando Bruno Gonçalves, Fabiano Severo Rodembusch
2019-01-28
Paper
DOI: 10.1039/C8CP05186K
Size and shape dependency of the surface energy of metallic nanoparticles: unifying the atomic and thermodynamic approaches
Bastiaan Molleman, Tjisse Hiemstra
2018-07-13
Paper
DOI: 10.1039/C8CP02346H
Analysis of the interfacial characteristics of BiVO4/metal oxide heterostructures and its implication on their junction properties
Sebastián Murcia-López, Andreas Klein, Roel van de Krol, Teresa Andreu, Joan Ramón Morante, Thierry Toupance, Wolfram Jaegermann
2019-01-29
Paper
DOI: 10.1039/C8CP07483F
Structural and bonding properties of Cu3O3− and Cu3O4− clusters: anion photoelectron spectroscopy and density functional calculations
Xi-Ling Xu, Bin Yang, Zhi-You Wei, Guo-Jin Cao, Hong-Guang Xu
2018-07-23
Paper
DOI: 10.1039/C8CP03302A
Dynamic micellar oligomers of amyloid beta peptides play a crucial role in their aggregation mechanisms
Bertrand Morel, Maria Paz Carrasco, Samuel Jurado, Carmen Marco, Francisco Conejero-Lara
2018-07-23
Paper
DOI: 10.1039/C8CP02685H
Three-dimensional pulsed field gradient NMR measurements of self-diffusion in anisotropic materials for energy storage applications
L. E. Marbella, N. M. Trease, M. De Volder, C. P. Grey
2019-01-28
Paper
DOI: 10.1039/C8CP07776B
Quantitative analysis of 14N quadrupolar coupling using 1H detected 14N solid-state NMR
James A. Jarvis, Maria Concistre, Richard W. Bounds, Ilya Kuprov, Marina Carravetta, Philip T. F. Williamson
2019-02-27
Paper
DOI: 10.1039/C8CP06276E
A computational study on the electrified Pt(111) surface by the cluster model
2019-02-28
Paper
DOI: 10.1039/C8CP07241H
Theoretical study of the adsorption of hydrogen on cobalt clusters
Kevin García-Díez, Julio Fernández-Fernández, María J. López
2018-07-20
Paper
DOI: 10.1039/C8CP03048K
Effect of an external electric field on capillary filling of water in hydrophilic silica nanochannels
Andres Rojano Crisson, Enrique Wagemann, Harvey A. Zambrano
2018-06-22
Paper
DOI: 10.1039/C8CP03186J
You might also like
Compound Q&A
Is 6-(3-Fluorophenyl)picolinic acid (CAS: 887982-40-3) safe?
6-(3-Fluorophenyl)picolinic acid is generally considered safe for laboratory use...
887982-40-36-(3-Fluorophenyl)pi...
Compound Q&A
What industries use (3R)-3-Pyrrolidinol (CAS: 2799-21-5)?
(3R)-3-Pyrrolidinol is used in the pharmaceutical industry as a precursor for dr...
2799-21-5(3R)-3-Pyrrolidinol
Compound Q&A
What precautions should be taken when handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-8)?
When handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-...
59779-75-8(4R,5R)-4,5-Diethoxy...
Compound Q&A
How is 1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone (CAS: 90734-71-7) typically synthesized?
1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone is often synthesized via a mult...
90734-71-71-(6-Chloroimidazo[1...
Compound Q&A
What is the market or research trend for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1)?
The market for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1) remains steady,...
39180-83-1N-Ethyl-3,4-dimethyl...
Compound Q&A
What is Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate (CAS: 1019008-21-9)?
Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate is a chemical compound wit...
1019008-21-9Tert-butyl 3-(pyrrol...
Compound Q&A
What regulatory guidelines apply to 1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1)?
1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1) falls under the classi...
1228956-93-11-Bromo-3-chloro-2,4...
Compound Q&A
Is 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07-4) safe?
The safety of 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07...
1368622-07-48-Bromo-2-methyl-3,4...
Compound Q&A
Is Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate (CAS: 22785-43-9) safe?
Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate is generally safe when handled wi...
22785-43-9Benzyl [(3S)-2,6-dio...
Compound Q&A
How should 1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine (CAS: 928657-21-0) be stored?
1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine s...
928657-21-01-{[4-(4,4,5,5-Tetra...
Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
Ethyl 6-(trifluoromethyl)pyridazine-3-carboxylate
CAS Number:
1192155-06-8
Molecular Formula:
C8H7F3N2O2
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.