Rhodium-catalyzed asymmetric phenylation of N-phosphinoylarylimines with triphenylborane‡
Literature Information
Xinyu Hao, Qian Chen, Masami Kuriyama, Ken-ichi Yamada, Yasutomo Yamamoto, Kiyoshi Tomioka
Triphenylborane asymmetrically transfers its phenyl group to N-diphenylphosphinoylarylimines to give diarylmethylamines with high ee in high yield without imine hydrolysis under the catalysis of a chiral amidomonophosphane–rhodium(I) complex.
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