Rhodium-catalyzed asymmetric phenylation of N-phosphinoylarylimines with triphenylborane‡

Literature Information

Publication Date 2011-02-04
DOI 10.1039/C0CY00083C
Impact Factor 6.119
Authors

Xinyu Hao, Qian Chen, Masami Kuriyama, Ken-ichi Yamada, Yasutomo Yamamoto, Kiyoshi Tomioka


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Abstract

Triphenylborane asymmetrically transfers its phenyl group to N-diphenylphosphinoylarylimines to give diarylmethylamines with high ee in high yield without imine hydrolysis under the catalysis of a chiral amidomonophosphane–rhodium(I) complex.

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Catalysis Science & Technology

Catalysis Science & Technology
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Self-citation Rate: 4.5%
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