A two-step field-induced magnetic transition in a novel layered cobalt diphosphonate

Literature Information

Publication Date 2003-03-31
DOI 10.1039/B212674E
Impact Factor 6.222
Authors

Ping Yin, Song Gao, Li-Min Zheng, Zheming Wang, Xin-Quan Xin


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Abstract

Compound Na6Co7(hedp)2(hedpH)4(H2O)4·8H2O (hedp = 1-hydroxyethylidenediphosphonate) with a novel layer structure is reported in this paper. The layer maybe viewed as made up from two types of chains each of composition Co3(hedp)2 and Co2(hedpH)2. Magnetic measurements at 1.8 K reveal a metamagnetic transition at ca. 6.5 kOe, followed by a second transition to a ferromagnetic state at ca. 30 kOe.

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