![1,10-bis(3,5-dimethylphenyl)-12-hydroxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine 12-oxide structure](https://static.chemtradehub.com/structs/141/1412439-82-7-b9a9.webp "1,10-bis(3,5-dimethylphenyl)-12-hydroxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine 12-oxide structure")
1,10-bis(3,5-dimethylphenyl)-12-hydroxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine 12-oxide
CAS Number:
1412439-82-7
Molecular Formula:
C33H31O4P
Synthesis of sulfur-containing poly(thioester)s with high refractive indices and high Abbe numbers
Literature Information
Publication Date
2010-01-07
DOI
10.1039/B9PY00326F
Impact Factor
5.582
Authors
Nam-Ho You, Tomoya Higashihara, Suzuki Yasuo, Shinji Ando, Mitsuru Ueda
View Original
Abstract
New poly(thioester)s (PTE)s containing sulfide and alicyclic units in polymer chains with high refractive indices and high Abbe numbers have been developed as thermoplastics. The PTEs were synthesized by the polycondensation reaction of 2,5-bis(sulfanylmethyl)-1,4-dithiane (BMMD) with 1,3-adamantanedicarbonyl dichloride (ADC) or cyclohexanedicarbonyl dichloride (CDC). Tough, flexible, and transparent amorphous polymer films were obtained. All polymers showed good thermal stability such as 5% weight-loss temperatures in the range 301–307 °C under nitrogen, and glass transition temperatures (Tg) in the range 65–110 °C. Poly(BMMD/ADC) and poly(BMMD/CDC) showed high refractive indices of 1.6149 and 1.6217, Abbe numbers of 32.1 and 30.0, respectively, and high transparency in the visible region.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
1-Isobutyl-7-methoxy-2,3,4,9-tetrahydro-1H-beta-carboline
CAS Number:
175975-76-5
Molecular Formula:
C16H22N2O
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