Time-resolved EPR observation of synthetic eumelanin–superoxide radical pairs
Literature Information
Antonio Toffoletti, Fosca Conti, Tommaso Sandron, Alessandra Napolitano, Lucia Panzella, Marco D’Ischia
TR-EPR spectra of UV irradiated synthetic eumelanin in equilibrium with air oxygen, reveal the formation of melanin–superoxide radical pairs and allow to determine both the electron dipolar interaction D and the exchange interaction J between the two radicals.
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![tert-Butyl N-[(2-chloropyridin-4-yl)methyl]carbamate structure tert-Butyl N-[(2-chloropyridin-4-yl)methyl]carbamate structure](https://static.chemtradehub.com/structs/916/916210-27-0-9f95.webp)

