Time-resolved EPR observation of synthetic eumelanin–superoxide radical pairs

Literature Information

Publication Date 2009-07-10
DOI 10.1039/B909568C
Impact Factor 6.222
Authors

Antonio Toffoletti, Fosca Conti, Tommaso Sandron, Alessandra Napolitano, Lucia Panzella, Marco D’Ischia


View Original

Abstract

TR-EPR spectra of UV irradiated synthetic eumelanin in equilibrium with air oxygen, reveal the formation of melanin–superoxide radical pairs and allow to determine both the electron dipolar interaction D and the exchange interaction J between the two radicals.

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Chemical Communications
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