A two-step spin crossover mononuclear iron(ii) complex with a [HS–LS–LS] intermediate phase

Literature Information

Publication Date 2008-09-29
DOI 10.1039/B811746B
Impact Factor 6.222
Authors

Sylvestre Bonnet, Maxime A. Siegler, José Sánchez Costa, Gábor Molnár, Azzedine Bousseksou, Anthony L. Spek, Patrick Gamez, Jan Reedijk


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Abstract

The two-step spin crossover of a new mononuclear iron(II) complex is studied by magnetic, crystallographic and calorimetric methods revealing two successive first-order phase transitions and an ordered intermediate phase built by the repetition of the unprecedented [HS–LS–LS] motif.

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Contents list

Front/Back Matter

DOI: 10.1039/C9CP90102G

Inside front cover

Cover

DOI: 10.1039/C9CP90116G

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