Formation of a stable dicarbenoid and an unsaturated C2P2S2 ring from two-electron oxidation of the [C(PPh2S)2]2− dianion

Literature Information

Publication Date 2008-09-12
DOI 10.1039/B810796C
Impact Factor 6.222
Authors

Jari Konu, Tristram Chivers


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Abstract

Two-electron oxidation of the [C(PPh2S)2]2− dianion with iodine afforded an unexpected mixture of a dimeric Li–I carbenoid [(Et2O)(μ-Li)][(μ4-Li){IC(PPh2S)2}2] and a novel, unsaturated six-membered C2P2S2 ring in [(SPh2P)2C2(PPh2)2S2].

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