Rhodium-catalysed cyclisation reaction of allenynes with arylboronic acids

Literature Information

Publication Date 2008-09-16
DOI 10.1039/B810665G
Impact Factor 6.222
Authors

Tomoya Miura, Keita Ueda, Yusuke Takahashi, Masahiro Murakami


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Abstract

Allenynes having malonate-based tethers reacted with arylboronic acids in the presence of a rhodium(I) catalyst to sequentially form three carbon–carbon bonds, and arylated bicyclic skeletons were constructed in a stereoselective manner.

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