The importance of solvent reorganisation in the effect of an ionic liquid on a unimolecular substitution process
Literature Information
Hon Man Yau, Susan A. Barnes, James M. Hook, Tristan G. A. Youngs, Anna K. Croft, Jason B. Harper
Temperature dependent rate studies demonstrate an enthalpic benefit and an entropic cost associated with the change in the rate of a unimolecular substitution process on addition of a high proportion of an ionic liquid, the latter effect being supported by molecular dynamics simulations.
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