Electropolymerization of 2-methoxyaniline. Polymerization kinetics and phenazine insertion at low monomer concentration
Literature Information
F. A. Viva, E. M. Andrade, M. I. Florit, F. V. Molina
The electropolymerization of 2-methoxyaniline (MOA) has been found to yield products having structure and properties dependent on the monomer concentration, with the insertion of phenazinic units giving a redox-type polymer at low concentrations. The kinetics of this process is studied in 1 M HClO4 solutions containing different monomer concentrations. The voltammetric results are compared with the electropolymerization, in similar experimental conditions, of other aryl amines such as aniline and 2-methylaniline. The effect of dimeric additives on the polymerization rate of MOA is also studied. A change in the kinetic behavior is found at MOA concentrations of about 30–60 mM. An electropolymerization mechanism for 2-methoxyaniline is proposed through a reaction scheme similar to that of aniline, with the inclusion of a step consisting in a head-to-head coupling of oligomers and/or polymer chains yielding phenazine-type units, that effectively works as a termination step. The resistivity increase, in the conductive state, due to the insertion of redox units is also considered. The experimental results are interpreted on the basis of this mechanism.
Related Literature
Simultaneous photo-induced polymerization and surface modification by microfluidic spinning to produce functionalized polymer microfibers: the effect of their surface modification on cell adhesion
Christophe A. Serra, Candice Dussouillez, Naji Kharouf, Irene Andrea Acuña Mejía, Antoine Kichler, Delphine Chan-Seng
DOI: 10.1039/D3LP00032J
Chitosan/PVA-supported silver nanoparticles for azo dyes removal: fabrication, characterization, and assessment of antioxidant activity
Ismet Meydan, Aysenur Aygun, Rima Nour Elhouda Tiri, Tugba Gur, Yılmaz Kocak, Hamdullah Seckin, Fatih Sen
DOI: 10.1039/D3VA00224A
Identification and functional characterization of novel plant UDP-glycosyltransferase (LbUGT72B10) for the bioremediation of 3,4-dichloroaniline
Valeria Della Gala, Ditte Hededam Welner
DOI: 10.1039/D3SU00220A
Facile synthesis of Z-scheme Fe-nPPy/BiOI nanocomposites for enhanced visible light driven photocatalytic activity
Rituporn Gogoi, Kajal Sharma, Astha Singh, Prem Felix Siril
DOI: 10.1039/D3VA00250K
Assessing sources and fractions of metals associated with environmental plastics: a case study in Lake Como (Italy)
Stefano Carnati, Andrea Pozzi, Davide Spanu, Damiano Monticelli, Roberta Bettinetti, Ginevra Boldrocchi
DOI: 10.1039/D3VA00254C
Thermoresponsive polymers with LCST transition: synthesis, characterization, and their impact on biomedical frontiers
Yichun Yuan, Konpal Raheja, Nathalie B. Milbrandt, Sophia Beilharz, Steffy Tene, Solomon Oshabaheebwa, Anna Cristina S. Samia, Metin Karayilan
DOI: 10.1039/D3LP00114H
A review on polyhydroxyalkanoate (PHA) production through the use of lignocellulosic biomass
Deepak Kumar, B. V. Ramarao
DOI: 10.1039/D3SU00126A
Predicting power plant emissions using public data and machine learning
Jiajun Gu, Jeffrey A. Sward, K. Max Zhang
DOI: 10.1039/D3VA00191A
You might also like
How should waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane be handled?
Waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane (...
How is 7-Fluoro-4-isoquinolinecarboxylic acid (CAS: 1841081-40-0) typically synthesized?
7-Fluoro-4-isoquinolinecarboxylic acid can be synthesized via a multi-step proce...
What are the physical and chemical properties of 2,3,5,6-Tetrabromothieno[3,2-b]thiophene (CAS: 124638-53-5)?
2,3,5,6-Tetrabromothieno[3,2-b]thiophene is a crystalline compound with a high m...
Is 1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indole-4-carboxamide (CAS: 1542705-92-9) safe?
1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indol...
What is the market or research trend for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3-methyl-4-oxo- (CAS: 113942-30-6)?
The market for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3...
What is 3-(Triisopropylsilyl)propiolaldehyde (CAS: 163271-80-5)?
3-(Triisopropylsilyl)propiolaldehyde is a synthetic organic compound with the CA...
What regulatory guidelines apply to 6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1)?
6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1) is subject to various regu...
How should waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piperazinyl)acetic acid (CAS: 885272-91-3) be handled?
Waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piper...
What are the physical and chemical properties of N,N'-4,4'-Biphenyldiyldiisonicotinamide (CAS: 55119-40-9)?
N,N'-4,4'-Biphenyldiyldiisonicotinamide is a white crystalline solid with a mole...
What industries use 6-Bromo-8-fluoro-2-quinazolinol (CAS: 1036756-15-6)?
6-Bromo-8-fluoro-2-quinazolinol is primarily used in the pharmaceutical industry...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![2,9-Dichloro-5,12-dihydroquinolino[2,3-b]acridine-7,14-dione structure 2,9-Dichloro-5,12-dihydroquinolino[2,3-b]acridine-7,14-dione structure](https://static.chemtradehub.com/structs/308/3089-17-6-750b.webp)



