Safe, facile radical-based reduction and hydrosilylation reactions in a microreactor using tris(trimethylsilyl)silane

Literature Information

Publication Date 2008-04-29
DOI 10.1039/B803715A
Impact Factor 6.222
Authors

Arjan Odedra, Karolin Geyer, Tomas Gustafsson, Ryan Gilmour, Peter H. Seeberger


View Original

Abstract

A highly efficient system for tris(trimethylsilyl)silane (TTMSS) mediated deoxygenation, dehalogenation and hydrosilylation reactions is described in a microstructured device; this convenient platform enables the scale up of radical-based processes.

Related Literature

Is there any fundamental difference between ionic, covalent, and others types of bond? A canonical perspective on the question

Jay R. Walton, Luis A. Rivera-Rivera, Robert R. Lucchese, John W. Bevan

2017-05-30 Paper

DOI: 10.1039/C7CP02407J

The role of the long-range tail of the potential in O2 + N2 collisional inelastic vibrational energy transfers

Ernesto Garcia, Fernando Pirani, Antonio Laganà, Carles Martí

2017-03-29 Paper

DOI: 10.1039/C7CP01340J

The role of liquid–liquid transition in glass formation of CuZr alloys

Xi Zhao, Chunzhen Wang, Haijiao Zheng, Zean Tian, Lina Hu

2017-05-31 Paper

DOI: 10.1039/C7CP02111A

Front cover

Cover

DOI: 10.1039/C7CP90128C

The effect of hydroxyl on the solution behavior of a quaternary ammonium gemini surfactant

Xuepeng Wu, Caili Dai, Sisi Fang, Hao Li, Yining Wu, Xin Sun, Mingwei Zhao

2017-05-30 Paper

DOI: 10.1039/C7CP00131B

Optimization of hydrophilic/hydrophobic phase separation in sPEEK membranes by hydrothermal treatments

H. Mendil-Jakani, I. Zamanillo López, V. H. Mareau, L. Gonon

2017-05-22 Paper

DOI: 10.1039/C7CP00087A

Aggregation of cyclic polypeptoids bearing zwitterionic end-groups with attractive dipole–dipole and solvophobic interactions: a study by small-angle neutron scattering and molecular dynamics simulation

Pu Du, Ang Li, Xin Li, Yueheng Zhang, Changwoo Do, Lilin He, Steven W. Rick, Vijay T. John, Revati Kumar, Donghui Zhang

2017-04-12 Paper

DOI: 10.1039/C7CP01602F

Extra electronic outer-shell peculiarities accessible under a joint XPS and DFT study

A. R. Cholach, A. A. Bryliakova

2017-05-22 Paper

DOI: 10.1039/C7CP00900C

Low loss optical waveguiding in large single crystals of a thiophene-based oligomer

Sajedeh Motamen, Christian Schörner, Dominic Raithel, Jean-Pierre Malval, Thibaut Jarrosson, Françoise Serein-Spirau, Laurent Simon, Richard Hildner, Günter Reiter

2017-06-01 Paper

DOI: 10.1039/C7CP01639E

You might also like

Compound Q&A

Are there alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3848-36-0) in synthesis?

When considering alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3...

3848-36-01-(4-Chlorophenyl)-N...
Compound Q&A

How is 3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole (CAS: 419553-16-5) typically synthesized?

3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole is synthesized through a m...

419553-16-53-(4-Bromophenyl)-5-...
Compound Q&A

How is 5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS: 1639220-19-1) typically synthesized?

5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS...

1639220-19-15-Chloro-2-(4-chloro...
Compound Q&A

What industries use 2-Chloro-4-(difluoromethoxy)pyridine (CAS: 1206978-15-5)?

2-Chloro-4-(difluoromethoxy)pyridine is used in the pharmaceutical industry for ...

1206978-15-52-Chloro-4-(difluoro...
Compound Q&A

What regulatory guidelines apply to 3-Chloro-6-methylpyridazine (CAS: 1121-79-5)?

3-Chloro-6-methylpyridazine (CAS: 1121-79-5) is classified under the Globally Ha...

1121-79-53-Chloro-6-methylpyr...
Compound Q&A

Are there alternatives to Methyl 4,5-dimethyl-2-nitrobenzoate in synthesis?

Several alternatives can be used in the synthesis of Methyl 4,5-dimethyl-2-nitro...

90922-74-0Methyl 4,5-dimethyl-...
Compound Q&A

Are there alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde in synthesis?

Alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde include other acry...

63405-68-5(2E,2'E)-3,3'-(1,4-P...
Compound Q&A

What is 3-Amino-5-chloropyridin-2-ol hydrochloride (CAS: 1261906-29-9)?

3-Amino-5-chloropyridin-2-ol hydrochloride is an organic compound with the CAS n...

1261906-29-93-Amino-5-chloropyri...
Compound Q&A

What precautions should be taken when handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one (CAS: 1092349-93-3)?

When handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one, it is essential to wear...

1092349-93-36,7-Difluoro-2,3-dih...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.