Rhodium-catalyzed enantioselective desymmetrization of bicyclic hydrazines with alkynylboronic esters

Literature Information

Publication Date 2008-05-08
DOI 10.1039/B803693D
Impact Factor 6.222
Authors

Stefano Crotti, Ferruccio Bertolini, Franco Macchia, Mauro Pineschi


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Abstract

The first successful asymmetric transfer of rhodium–alkynyl species to symmetrical strained alkenes has been realized starting from bicyclic hydrazines and alkynylboronic esters.

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