Monovalent indium in a sulfur-rich coordination environment: synthesis, structure and reactivity of tris(2-mercapto-1-tert-butylimidazolyl)hydroborato indium, [TmBut]In

Literature Information

Publication Date 2008-06-02
DOI 10.1039/B803037E
Impact Factor 6.222
Authors

Kevin Yurkerwich, Daniela Buccella, Jonathan G. Melnick, Gerard Parkin


View Original

Abstract

[TmBut]In, the first structurally-characterized monovalent indium compound that features a sulfur-rich coordination environment, has been synthesized via treatment of InCl with [TmBut]K; in contrast to the thallium counterpart, the lone pair of [TmBut]In is a site of reactivity, thereby allowing formation of [TmBut]In→B(C6F5)3 and [TmBut]In(κ2-S4) upon treatment with B(C6F5)3 and S8, respectively.

Related Literature

Ultrafast energy transfer within the photosystem II core complex

Jie Pan, Vladimir Chorošajev, Mikas Vengris, S. Seckin Senlik, Jian-Ren Shen, Darius Abramavicius, Jennifer P. Ogilvie

2017-05-23 Paper

DOI: 10.1039/C7CP01673E

Inside front cover

Cover

DOI: 10.1039/C7CP90129A

Specific DNA sequences allosterically enhance protein–protein interaction in a transcription factor through modulation of protein dynamics: implications for specificity of gene regulation

Abhishek Mazumder, Subrata Batabyal, Manas Mondal, Tanumoy Mondol, Susobhan Choudhury, Raka Ghosh, Tanaya Chatterjee, Dhananjay Bhattacharyya, Samir Kumar Pal, Siddhartha Roy

2017-05-26 Paper

DOI: 10.1039/C7CP01193H

Preparation and characterization of a calcium–phosphate–silicon coating on a Mg–Zn–Ca alloy via two-step micro-arc oxidation

Jinhe Dou, Yang Chen, Yiming Chi, Huancai Li, Guochao Gu, Chuanzhong Chen

2017-05-19 Paper

DOI: 10.1039/C7CP02672B

The role of liquid–liquid transition in glass formation of CuZr alloys

Xi Zhao, Chunzhen Wang, Haijiao Zheng, Zean Tian, Lina Hu

2017-05-31 Paper

DOI: 10.1039/C7CP02111A

The atmospheric oxidation of CH3OOH by the OH radical: the effect of water vapor

Josep M. Anglada, Ramon Crehuet, Marilia Martins-Costa, Joseph S. Francisco, Manuel Ruiz-López

2017-04-13 Paper

DOI: 10.1039/C7CP01976A

Structure and dynamics of [NH2(CH3)2]3Sb2Cl9 by means of 1H NMR relaxometry – quadrupolar relaxation enhancement effects

M. Florek-Wojciechowska, R. Jakubas, D. Kruk

2017-04-13 Paper

DOI: 10.1039/C7CP00788D

Low loss optical waveguiding in large single crystals of a thiophene-based oligomer

Sajedeh Motamen, Christian Schörner, Dominic Raithel, Jean-Pierre Malval, Thibaut Jarrosson, Françoise Serein-Spirau, Laurent Simon, Richard Hildner, Günter Reiter

2017-06-01 Paper

DOI: 10.1039/C7CP01639E

You might also like

Compound Q&A

Are there alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3848-36-0) in synthesis?

When considering alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3...

3848-36-01-(4-Chlorophenyl)-N...
Compound Q&A

How is 3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole (CAS: 419553-16-5) typically synthesized?

3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole is synthesized through a m...

419553-16-53-(4-Bromophenyl)-5-...
Compound Q&A

How is 5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS: 1639220-19-1) typically synthesized?

5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS...

1639220-19-15-Chloro-2-(4-chloro...
Compound Q&A

What industries use 2-Chloro-4-(difluoromethoxy)pyridine (CAS: 1206978-15-5)?

2-Chloro-4-(difluoromethoxy)pyridine is used in the pharmaceutical industry for ...

1206978-15-52-Chloro-4-(difluoro...
Compound Q&A

What regulatory guidelines apply to 3-Chloro-6-methylpyridazine (CAS: 1121-79-5)?

3-Chloro-6-methylpyridazine (CAS: 1121-79-5) is classified under the Globally Ha...

1121-79-53-Chloro-6-methylpyr...
Compound Q&A

Are there alternatives to Methyl 4,5-dimethyl-2-nitrobenzoate in synthesis?

Several alternatives can be used in the synthesis of Methyl 4,5-dimethyl-2-nitro...

90922-74-0Methyl 4,5-dimethyl-...
Compound Q&A

Are there alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde in synthesis?

Alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde include other acry...

63405-68-5(2E,2'E)-3,3'-(1,4-P...
Compound Q&A

What is 3-Amino-5-chloropyridin-2-ol hydrochloride (CAS: 1261906-29-9)?

3-Amino-5-chloropyridin-2-ol hydrochloride is an organic compound with the CAS n...

1261906-29-93-Amino-5-chloropyri...
Compound Q&A

What precautions should be taken when handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one (CAS: 1092349-93-3)?

When handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one, it is essential to wear...

1092349-93-36,7-Difluoro-2,3-dih...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.