Unusual parallel and inclined interlocking modes in polyrotaxane-like metal–organic frameworks

Literature Information

Publication Date 2008-03-10
DOI 10.1039/B800199E
Impact Factor 6.222
Authors

Jin Yang, Jian-Fang Ma, Stuart R. Batten, Zhong-Min Su


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Abstract

We describe here two unusual polyrotaxane-like metal–organic frameworks of [Co2(1,3-bix)2(bpea)2] 1 and [Cd4(1,4-bix)4(bpea)4]·4H2O 2, where both species contain loops and rods that are interlaced in a highly rare “parallel” fashion in 1, but, uniquely, in an “inclined” fashion in 2.

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