Direct evidence for an iron(iv)-oxo porphyrin π-cation radical as an active oxidant in catalytic oxygenation reactions

Literature Information

Publication Date 2008-01-03
DOI 10.1039/B716558G
Impact Factor 6.222
Authors

Ah-Rim Han, Yu Jin Jeong, Yaeun Kang, Jung Yoon Lee, Mi Sook Seo, Wonwoo Nam


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Abstract

A high-valent iron(IV)-oxo porphyrin π-cation radical is an active oxidant in the catalytic oxygenation of organic substrates by an iron(III) porphyrin complex and peracids, whereas an iron(III)-oxidant porphyrin adduct is a sluggish oxidant in iron porphyrin model reactions.

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