Heat-set gels and egg-like vesicles using two component gel system based on chiral calix[4]arenes

Literature Information

Publication Date 2007-10-12
DOI 10.1039/B713548C
Impact Factor 6.222
Authors

Xian-Jie Chen


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Abstract

Chiral calix[4]arenes bearing long tertiary alkyl groups at the upper rim and S-1-phenylethylamine groups at the lower rim can form heat-set gels and egg-like vesicles enantioselectively with D-2,3-dibenzoyltartaric acid in cyclohexane, which is the first example of heat-set gels resulting from difference in interactions between two component gelators: in addition, the diameter of vesicles decreased with the increase in length of alkyl groups, which could be used to control the size of the vesicles.

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