Air-stable and efficient inorganic–organic heterojunction solar cells using PbS colloidal quantum dots co-capped by 1-dodecanethiol and oleic acid
Literature Information
Sang Hyuk Im, Meejae Kang, Jin Hyuck Heo, Sang Il Seok, Sang-Wook Kim, Iván Mora-Seró, Juan Bisquert
PbS colloidal quantum dot (CQD)-sensitized inorganic–organic heterojunction solar cells fabricated by using the PbS CQDs co-capped by the oleic acid (OA) and 1-dodecanethiol (DT) ligand showed better device stability with aging time under ambient conditions without encapsulation. Furthermore, the device performance is better than the cell fabricated from PbS CQDs without DT ligand. The enhancement of performance in OA and DT co-capped systems is investigated by impedance spectroscopy. An upward displacement of the TiO2 conduction band, with a consequent increase of Voc, results in the improved performance when CQD with DT are employed.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











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