Insertion of benzyl isocyanide into a Zr–P bond and rearrangement. Atom-economical synthesis of a phosphaalkene
Literature Information
Samantha N. MacMillan, Joseph M. Tanski, Rory Waterman
Reaction of (N3N)ZrPHPh (1, N3N = N(CH2CH2NSiMe3)33−) with PhCH2NC affords the 1,1-insertion product (N3N)Zr[C(PHPh)NCH2Ph] (2), which thermally rearranges to the phosphaalkene-containing complex, (N3N)Zr[N(CH2Ph)C(H)PPh] (3).
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