Insertion of benzyl isocyanide into a Zr–P bond and rearrangement. Atom-economical synthesis of a phosphaalkene

Literature Information

Publication Date 2007-08-07
DOI 10.1039/B709506F
Impact Factor 6.222
Authors

Samantha N. MacMillan, Joseph M. Tanski, Rory Waterman


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Abstract

Reaction of (N3N)ZrPHPh (1, N3N = N(CH2CH2NSiMe3)33−) with PhCH2NC affords the 1,1-insertion product (N3N)Zr[C(PHPh)NCH2Ph] (2), which thermally rearranges to the phosphaalkene-containing complex, (N3N)Zr[N(CH2Ph)C(H)PPh] (3).

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