Dehydropolymerization of arylsilanes catalyzed by a novel silylmolybdenum complex

Literature Information

Publication Date 2003-11-03
DOI 10.1039/B310663M
Impact Factor 6.222
Authors

Makoto Minato, Takaomi Matsumoto, Miyuki Ichikawa, Takashi Ito


View Original

Abstract

A complex [MoH3{Si(Ph)[Ph2PCH2CH2P(Ph)C6H4-o]2}] (1) can act as single-component catalyst for dehydrogenative polymerization of ArSiH2R (Ar = Ph, p-tolyl, o-tolyl; R = H, Me) to (ArSiR)n: p- and o- tolylsilane produced the polymers of respectable molecular weights (Mw of 17300 and 6700 respectively) and polymerization of secondary silane, methylphenylsilane, gave a substantial molecular weight (Mw of 1750).

Related Literature

Growing polymers from peptides and proteins: a biomedical perspective

Yizhi Qi

2013-10-11 Review Article

DOI: 10.1039/C3PY01089A

Post-metalation of porous aromatic frameworks for highly efficient carbon capture from CO2 + N2 and CH4 + N2 mixtures

Heping Ma, Hao Ren, Xiaoqin Zou, Shuang Meng, Fuxing Sun

2013-07-24 Paper

DOI: 10.1039/C3PY00647F

Acetyl protected thiol methacrylic polymers as effective ligands to keep quantum dots in luminescent standby mode

Marta Liras, Isabel Quijada-Garrido, Marta Palacios-Cuesta, Sonia Muñoz-Durieux, Olga García

2013-08-30 Paper

DOI: 10.1039/C3PY00987D

An “active” and self-switchable nanoreactor

Bo Peng, Xinhua Yuan, Maiyong Zhu, Songjun Li

2013-08-30 Paper

DOI: 10.1039/C3PY01074K

One pot synthesis and characterization of novel poly(ether ester) mutiblock copolymers containing poly(tetramethylene oxide) and poly(ethylene terephthalate)

Weichun Huang, Yingbo Wan, Jianying Chen, Qiaozhen Xu, Xiaohong Li, Xiaoming Yang, Yaowen Li, Yingfeng Tu

2013-10-18 Paper

DOI: 10.1039/C3PY00932G

Combining surface topography with polymer chemistry: exploring new interfacial biological phenomena

Dan Li, Qing Zheng, Yanwei Wang, Hong Chen

2013-07-29 Review Article

DOI: 10.1039/C3PY00739A

Polymer patchy colloids with sticky patches

Yi Zhao, Rüdiger Berger, Katharina Landfester, Daniel Crespy

2013-09-12 Paper

DOI: 10.1039/C3PY01096A

Porphyrin-containing hyperbranched supramolecular polymers: enhancing 1O2-generation efficiency by supramolecular polymerization

Yiliu Liu, Zehuan Huang, Kai Liu, Hans Kelgtermans, Wim Dehaen, Zhiqiang Wang, Xi Zhang

2013-08-22 Communication

DOI: 10.1039/C3PY01036H

Reversibly crosslinked thermo- and redox-responsive nanogels for controlled drug release

Christophe Detrembleur, Marie Hurtgen, Antoine Debuigne, Marie-Claire De Pauw-Gillet, Stéphane Mornet, Etienne Duguet, Christine Jérôme

2013-07-31 Paper

DOI: 10.1039/C3PY00839H

You might also like

Compound Q&A

What are the main uses of 1H-Indazole-6-carbonitrile (CAS: 141290-59-7)?

1H-Indazole-6-carbonitrile finds applications in pharmaceuticals, where it serve...

141290-59-71H-Indazole-6-carbon...
Compound Q&A

How should waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) be handled?

Waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) should be collecte...

2997-85-5Dioctyl (2E)-2-buten...
Compound Q&A

What industries use Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide (CAS: 68291-98-5)?

Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide is primarily used in pharmac...

68291-98-5Sodium [(1,2-benzoxa...
Compound Q&A

Are there alternatives to Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxylate (CAS: 741709-66-0) in synthesis?

Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxyla...

741709-66-0Dimethyl 4-(4,4,5,5-...
Compound Q&A

How should waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) be handled?

Waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) should be manage...

80714-39-22-Fluoro-6-hydrazino...
Compound Q&A

What is 6-Formyl-2-pyridinecarboxylic acid (CAS: 499214-11-8)?

6-Formyl-2-pyridinecarboxylic acid is an organic compound with the molecular for...

499214-11-86-Formyl-2-pyridinec...
900874-91-13-(3,4-dimethoxyphen...
Compound Q&A

How is 9H-Tribenzo[b,d,f]azepine (CAS: 29875-73-8) typically synthesized?

9H-Tribenzo[b,d,f]azepine is typically synthesized via a multi-step process invo...

29875-73-89H-Tribenzo[b,d,f]az...
Compound Q&A

How is 1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxylic acid (CAS: 1797982-51-4) typically synthesized?

1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxyli...

1797982-51-41-Cyclopropyl-7-etho...
Compound Q&A

How should waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: 671820-52-3) be handled?

Waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: ...

671820-52-3Methyl 3-oxo-1,2,3,4...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.