Pore size effects in the pyrolysis of 1,3-diphenylpropane confined in mesoporous silicas

Literature Information

Publication Date 2003-10-15
DOI 10.1039/B310405B
Impact Factor 6.222
Authors

Michelle K. Kidder, Phillip F. Britt, Zongtao Zhang, Sheng Dai, A. C. Buchanan, III


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Abstract

A new method for derivatizing mesoporous silicas, SBA-15 and MCM-41, with a substituted phenol is described, and pore confinement and surface curvature are shown to impact the reaction rate and product selectivity for the pyrolysis of surface-immobilized 1,3-diphenylpropane.

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