Exploration of the pentacyano-cyclo-pentadienide ion, C5(CN)5−, as a weakly coordinating anion and potential superacid conjugate base. Silylation and protonation

Literature Information

Publication Date 2004-02-16
DOI 10.1039/B316122F
Impact Factor 6.222
Authors

Christopher Richardson, Christopher A. Reed


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Abstract

The reportedly unprotonatable pentacyano-cyclo-pentadienide ion, C5(CN)5−, can be protonated and silylated at the cyano N atom using electrophilic reagents derived from weakly coordinating carborane anions.

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