Competitive O–H and C–H oxidative addition of CH3OH to rhodium(ii) porphyrins

Literature Information

Publication Date 2007-08-29
DOI 10.1039/B708032H
Impact Factor 6.222
Authors

Shan Li, Weihong Cui, Bradford B. Wayland


View Original

Abstract

Rhodium(II) porphyrins react with CH3OH in benzene by alternate mechanisms that give H–CH2OH and H–OCH3 bond activation in different methanol concentration regimes which is a rare example of transition metal reactivity with methanol.

Related Literature

Generation of strong, homochiral bases by electrochemical reduction of phenazine derivatives

A. Mateo Alonso, Roberto Horcajada, Helen J. Groombridge, Reshma Mandalia, Majid Motevalli, James H. P. Utley, Peter B. Wyatt

2004-01-20 Communication

DOI: 10.1039/B313995F

Synthesis of poly(para-phenylenevinylene) rotaxanes by aqueous Suzuki coupling

Jun Terao, Andrew Tang, Jasper J. Michels, Alexander Krivokapic, Harry L. Anderson

2003-11-27 Communication

DOI: 10.1039/B311762F

Pore size effects in the pyrolysis of 1,3-diphenylpropane confined in mesoporous silicas

Michelle K. Kidder, Phillip F. Britt, Zongtao Zhang, Sheng Dai, A. C. Buchanan, III

2003-10-15 Communication

DOI: 10.1039/B310405B

The kinetics of propene and hexenepolymerisation with [(SBI)ZrR]+X−: evidence for monomer-dependent early or late transition states

Fuquan Song, Roderick D. Cannon, Manfred Bochmann

2004-02-05 Communication

DOI: 10.1039/B314845A

The first general method for α-trifluoromethylation of carboxylic acids using BrF3

Aviv Hagooly, Shlomo Rozen

2004-02-09 Communication

DOI: 10.1039/B315705A

A novel azulene synthesis from the Ramirez ylide involving two different modes of its reaction with activated alkynes

Lee J. Higham, P. Gabriel Kelly, David M. Corr, Helge Müller-Bunz, Brian J. Walker, Declan G. Gilheany

2004-02-11 Communication

DOI: 10.1039/B316759C

Stabilization of D5h and C2v valence tautomers of the croconate dianion

Chi-Keung Lam, Mei-Fun Cheng, Chi-Lun Li, Jie-Peng Zhang, Xiao-Ming Chen, Wai-Kee Li, Thomas C. W. Mak

2003-12-18 Communication

DOI: 10.1039/B312545A

Electrochemical wiring of α,ω-alkanedithiol molecules into an electrical circuit

Renata Bilewicz, Krzysztof Slowinski

2004-01-23 Communication

DOI: 10.1039/B314815G

Very general formation of tetrahydropterincation radicals during reaction of iron porphyrins with tetrahydropterins: model for the corresponding NO-synthase reaction

Delphine Mathieu, Yves-Michel Frapart, Jean François Bartoli, Jean-Luc Boucher, Pierrette Battioni, Daniel Mansuy

2003-12-02 Communication

DOI: 10.1039/B312441J

You might also like

Compound Q&A

How should waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) be handled?

Waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) ...

88634-80-42-Ethyl-4-Methyl-1H-...
Compound Q&A

What industries use Triethoxy(octyl)silane (CAS: 1385031-14-0)?

Triethoxy(octyl)silane (CAS: 1385031-14-0) is widely used in the pharmaceuticals...

1385031-14-0Triethoxy(octyl)sila...
Compound Q&A

Are there alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) in synthesis?

Several alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) exist in t...

864724-64-13-iodo-7-nitro-1H-in...
Compound Q&A

Are there alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317-71-9) in synthesis?

Yes, there are alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317...

266317-71-9Benzene, bis[(trimet...
Compound Q&A

Is Isothiazole-3-carbonitrile (CAS: 1452-17-1) safe?

Isothiazole-3-carbonitrile (CAS: 1452-17-1) is generally considered safe when us...

1452-17-1Isothiazole-3-carbon...
Compound Q&A

Is (3-Chlorophenyl)methanol (CAS: 873-63-2) safe?

(3-Chlorophenyl)methanol (CAS: 873-63-2) is considered low to moderately toxic. ...

873-63-2(3-Chlorophenyl)meth...
Compound Q&A

How is (2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)propanoic acid (CAS: 959583-98-3) typically synthesized?

(2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)pr...

959583-98-3(2S,3S)-2-Hydroxy-3-...
Compound Q&A

What precautions should be taken when handling Methyl 2-(bromomethyl)-5-methoxybenzoate (CAS: 788081-99-2)?

Proper handling of methyl 2-(bromomethyl)-5-methoxybenzoate requires the use of ...

788081-99-2Methyl 2-(bromomethy...
Compound Q&A

What is 6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3)?

6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3) is an aro...

904805-36-36,8-Dibromoimidazo[1...
Compound Q&A

Is 3-Amino-5-bromo-2-pyridinecarbonitrile (CAS: 573675-27-1) safe?

3-Amino-5-bromo-2-pyridinecarbonitrile is considered safe when handled under pro...

573675-27-13-Amino-5-bromo-2-py...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.