Competitive O–H and C–H oxidative addition of CH3OH to rhodium(ii) porphyrins
Literature Information
Shan Li, Weihong Cui, Bradford B. Wayland
Rhodium(II) porphyrins react with CH3OH in benzene by alternate mechanisms that give H–CH2OH and H–OCH3 bond activation in different methanol concentration regimes which is a rare example of transition metal reactivity with methanol.
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![4-(4-{4-[4-Fluoro-3-(trifluoromethyl)phenyl]-1-methyl-1H-imidazol-2-yl}-1-piperidinyl)-1H-pyrazolo[3,4-d]pyrimidine 4-methylbenzenesulfonate (1:1) structure 4-(4-{4-[4-Fluoro-3-(trifluoromethyl)phenyl]-1-methyl-1H-imidazol-2-yl}-1-piperidinyl)-1H-pyrazolo[3,4-d]pyrimidine 4-methylbenzenesulfonate (1:1) structure](https://static.chemtradehub.com/structs/108/1082949-68-5-00b6.webp)



