Competitive O–H and C–H oxidative addition of CH3OH to rhodium(ii) porphyrins

Literature Information

Publication Date 2007-08-29
DOI 10.1039/B708032H
Impact Factor 6.222
Authors

Shan Li, Weihong Cui, Bradford B. Wayland


View Original

Abstract

Rhodium(II) porphyrins react with CH3OH in benzene by alternate mechanisms that give H–CH2OH and H–OCH3 bond activation in different methanol concentration regimes which is a rare example of transition metal reactivity with methanol.

Related Literature

Easy access to diastereomerically pure platinacycles

Concepción López, Amparo Caubet, Sonia Pérez, Xavier Solans, Mercè Font-Bardía

2004-01-27 Communication

DOI: 10.1039/B315157C

High quality CdSeS nanocrystals synthesized by facile single injection process and their electroluminescence

Eunjoo Jang, Shinae Jun, Lyongsun Pu

2003-11-07 Communication

DOI: 10.1039/B310853H

Living cationic polymerisation of styrene in an ionic liquid

R. Vijayaraghavan, D. R. MacFarlane

2004-02-13 Communication

DOI: 10.1039/B315100J

The synthesis of a di-N-heterocyclic carbene-amido complex of palladium(ii)

Richard E. Douthwaite, Jennifer Houghton, Benson M. Kariuki

2004-02-13 Communication

DOI: 10.1039/B314814A

Surface energy and surface area measurements by 19F MAS NMR of adsorbed trifluoroacetic acid

Vitaliy L. Budarin, James H. Clark, Stewart J. Tavener

2004-02-05 Communication

DOI: 10.1039/B315005D

Prediction of formation constants of metal–ammonia complexes in aqueous solution using density functional theory calculations

Robert D. Hancock, Libero J. Bartolotti

2004-01-27 Communication

DOI: 10.1039/B312518C

Template-free synthesis of single-crystalline cadmium nanotubes

Pingàn Hu, Yunqi Liu, Lei Fu, Lingchao Cao, Daoben Zhu

2004-02-04 Communication

DOI: 10.1039/B312708G

Very general formation of tetrahydropterincation radicals during reaction of iron porphyrins with tetrahydropterins: model for the corresponding NO-synthase reaction

Delphine Mathieu, Yves-Michel Frapart, Jean François Bartoli, Jean-Luc Boucher, Pierrette Battioni, Daniel Mansuy

2003-12-02 Communication

DOI: 10.1039/B312441J

Controlled functionalization of gold nanoparticles through a solid phase synthesis approach

James G. Worden, Andrew W. Shaffer, Qun Huo

2004-02-04 Communication

DOI: 10.1039/B312819A

Relative importance of hydrogen bonding and coordinating groups in modulating the zinc–water acidity

Juan C. Mareque-Rivas, Ravi Prabaharan, Rafael Torres Martín de Rosales

2003-11-04 Communication

DOI: 10.1039/B310956A

You might also like

Compound Q&A

How should waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) be handled?

Waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) ...

88634-80-42-Ethyl-4-Methyl-1H-...
Compound Q&A

What industries use Triethoxy(octyl)silane (CAS: 1385031-14-0)?

Triethoxy(octyl)silane (CAS: 1385031-14-0) is widely used in the pharmaceuticals...

1385031-14-0Triethoxy(octyl)sila...
Compound Q&A

Are there alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) in synthesis?

Several alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) exist in t...

864724-64-13-iodo-7-nitro-1H-in...
Compound Q&A

Are there alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317-71-9) in synthesis?

Yes, there are alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317...

266317-71-9Benzene, bis[(trimet...
Compound Q&A

Is Isothiazole-3-carbonitrile (CAS: 1452-17-1) safe?

Isothiazole-3-carbonitrile (CAS: 1452-17-1) is generally considered safe when us...

1452-17-1Isothiazole-3-carbon...
Compound Q&A

Is (3-Chlorophenyl)methanol (CAS: 873-63-2) safe?

(3-Chlorophenyl)methanol (CAS: 873-63-2) is considered low to moderately toxic. ...

873-63-2(3-Chlorophenyl)meth...
Compound Q&A

How is (2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)propanoic acid (CAS: 959583-98-3) typically synthesized?

(2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)pr...

959583-98-3(2S,3S)-2-Hydroxy-3-...
Compound Q&A

What precautions should be taken when handling Methyl 2-(bromomethyl)-5-methoxybenzoate (CAS: 788081-99-2)?

Proper handling of methyl 2-(bromomethyl)-5-methoxybenzoate requires the use of ...

788081-99-2Methyl 2-(bromomethy...
Compound Q&A

What is 6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3)?

6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3) is an aro...

904805-36-36,8-Dibromoimidazo[1...
Compound Q&A

Is 3-Amino-5-bromo-2-pyridinecarbonitrile (CAS: 573675-27-1) safe?

3-Amino-5-bromo-2-pyridinecarbonitrile is considered safe when handled under pro...

573675-27-13-Amino-5-bromo-2-py...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.